Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Romana Mičová"'
Autor:
Romana Mičová, Cyril Rajnák, Ján Titiš, Erika Samoľová, Michal Zalibera, Alina Bieńko, Roman Boča
Publikováno v:
Chemical Communications. 59:2612-2615
AC susceptibility confirms a field supported slow magnetic relaxation in which the over-barrier Orbach relaxation process does not play a role. Both systems possess two or three slow relaxation channels.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e80addb51a10e006e6391b708250348f
https://doi.org/10.1039/d2cc06510j
https://doi.org/10.1039/d2cc06510j
Publikováno v:
New Journal of Chemistry. 46:22686-22691
Two novel 1D chains based on heptacoordinated Mn(ii) ions bridged by variously derived benzoate ligands were prepared.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::76de90e5299fcafa8130600581556c52
https://doi.org/10.1039/d2nj04131f
https://doi.org/10.1039/d2nj04131f
Autor:
Romana Mičová, Zuzana Bielková, Cyril Rajnák, Ján Titiš, Milan Gembický, Franz Renz, Ondřej Malina, Erika Samoľová, Jana Nováčiková, Roman Boča
Publikováno v:
New Journal of Chemistry. 46:18083-18089
A new series of Fe(iii) mononuclear complexes of the [Fe(Lam)(X)] type {where X = Cl (1), NCSe (2), NCS (3), N3 (4), and NCO (5)} have been prepared and characterized in detail.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::79f1cc821aca4e81c7969a3f4e5cb1a9
https://doi.org/10.1039/d2nj02294j
https://doi.org/10.1039/d2nj02294j
Publikováno v:
Dalton Transactions.
Complexes under study exhibit field-supported SMR. For 1, the relaxation time at T = 2.0 K is τHF = 20 and 2 ms at the applied field BDC = 0.15 and 0.35 T, respectively. For 2 at T = 2.0 K and BDC = 0.1 T, the relaxation time is τHF = 6 ms.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::de77e980f39c654867b5bc3f9c29e388
https://doi.org/10.1039/d3dt00990d
https://doi.org/10.1039/d3dt00990d
Autor:
Christoph Krüger, Roman Boča, Ľubor Dlháň, Franz Renz, Ján Moncoľ, Romana Mičová, Cyril Rajnák
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 50(2)
A pentadentate Schiff-base ligand 3,5Cl-L2- and NCSe- form an iron(iii) mononuclear complex, namely [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6bee431233b27dc0ec59d1e7df9d4089
https://pubmed.ncbi.nlm.nih.gov/33350428
https://pubmed.ncbi.nlm.nih.gov/33350428