Zobrazeno 1 - 10
of 102
pro vyhledávání: '"Roman Boulatov"'
Publikováno v:
Nature Communications, Vol 14, Iss 1, Pp 1-10 (2023)
Abstract Allosteric control of reaction thermodynamics is well understood, but the mechanisms by which changes in local geometries of receptor sites lower activation reaction barriers in electronically uncoupled, remote reaction moieties remain relat
Externí odkaz:
https://doaj.org/article/ed4e1410ac60421583306f0efce95dd5
Autor:
Chenxu Wang, Sergey Akbulatov, Qihan Chen, Yancong Tian, Cai-Li Sun, Marc Couty, Roman Boulatov
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-13 (2022)
Large mechanical loads usually degrade polymers by accelerating fragmentation of their backbones but rarely, they can cause new backbone bonds to form leading to arrested or reversed degradation when new bonds are formed faster than the original bond
Externí odkaz:
https://doaj.org/article/875725e9901a41f4812da6189b1f6d84
Autor:
Huan Zhang, Xun Li, Yangju Lin, Fei Gao, Zhen Tang, Peifeng Su, Wenke Zhang, Yuanze Xu, Wengui Weng, Roman Boulatov
Publikováno v:
Nature Communications, Vol 8, Iss 1, Pp 1-10 (2017)
Mechanochemistry offers exciting opportunities for molecular engineering of stress-responsive properties of polymers. Here the authors show that macrocyclic cinnamate dimers in a polymer chain can undergo dissociation on the sub-second timescale unde
Externí odkaz:
https://doaj.org/article/bbd24677f9464fa0a04eceeb58c2bca3
Publikováno v:
Nature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
Polymer mechanochemistry offers opportunities to control and engineer desired chemical transformations. Here, Craig and co-workers present a mechanical gating system whereby one mechanophore modulates the reactivity of another, resulting in a mechano
Externí odkaz:
https://doaj.org/article/2ee6aef122ab46d38cd3f3f3723469fe
Autor:
Antony P. Y. Chan, Martin Jakoobi, Chenxu Wang, Robert T. O’Neill, Gülsevim S. S. Aydin, Nathan Halcovitch, Roman Boulatov, Alexey G. Sergeev
Publikováno v:
Journal of the American Chemical Society. 144:11564-11568
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f80f55a18a9bd7c66a633d8bab862911
https://doi.org/10.1021/jacs.2c04621
https://doi.org/10.1021/jacs.2c04621
Autor:
Robert T. O'Neill, Roman Boulatov
Publikováno v:
Molecular Photoswitches. :253-281
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::74ded2be377dc917672bc3687302e193
https://doi.org/10.1002/9783527827626.ch12
https://doi.org/10.1002/9783527827626.ch12
Autor:
Roman Boulatov, Robert T. O’Neill
Publikováno v:
SYNLETT
The exciting field of polymer mechanochemistry has made great empirical progress in discovering reactions in which a stretching force accelerates scission of strained bonds using single molecule force spectroscopy and ultrasonication experiments. Und
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f5d7073feda8775825d1cdbfbf3c3843
https://doi.org/10.1055/a-1710-5656
https://doi.org/10.1055/a-1710-5656
Autor:
Liqi Wang, Yichen Yu, Chenxu Wang, Ross A. Widenhoefer, Stephen L. Craig, Roman Boulatov, Cai-Li Sun
Publikováno v:
Chemical Science
CHEMICAL SCIENCE
CHEMICAL SCIENCE
Coupled mechanical forces are known to drive a range of covalent chemical reactions, but the effect of mechanical force applied to a spectator ligand on transition metal reactivity is relatively unexplored. Here we quantify the rate of C(sp2)–C(sp2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d94427019331359dee16a7947c472af1
https://doi.org/10.1039/d1sc03182a
https://doi.org/10.1039/d1sc03182a
Autor:
Antony P Y, Chan, Martin, Jakoobi, Chenxu, Wang, Robert T, O'Neill, Gülsevim S S, Aydin, Nathan, Halcovitch, Roman, Boulatov, Alexey G, Sergeev
Publikováno v:
Journal of the American Chemical Society. 144(26)
Aromatic C-H activation in alkylarenes is a key step for the synthesis of functionalized organic molecules from simple hydrocarbon precursors. Known examples of such C-H activations often yield mixtures of products resulting from activation of the le
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::3d9e0da4490c02ecce37de3f4bdfc430
https://pubmed.ncbi.nlm.nih.gov/35728272
https://pubmed.ncbi.nlm.nih.gov/35728272
Publikováno v:
CCS Chemistry. 2:1391-1398
Structural modifications are a successful and commonly used approach to tune the emission properties of diverse fluorophores, but extending this approach to heavy-atom-free persistent luminophores ...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::aec7426c18a8386f872864edbc85e441
https://doi.org/10.31635/ccschem.020.202000158
https://doi.org/10.31635/ccschem.020.202000158