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pro vyhledávání: '"Rolf Sigrist"'
Autor:
Rolf Sigrist, Hans-Jürgen Hansen
Publikováno v:
Helvetica Chimica Acta. 97:1165-1175
The oxidation of benzo[a]azulene (4) with commercial MnO2 in dioxane/H2O leads to a number of products in low yield (Table 1). Treatment of 4 with ‘mild’ MnO2 (MnO2/C) in dioxane/5% H2O results in the formation of 10,10′-bibenzo[a]azulene (18)
Autor:
Hans-Jürgen Hansen, Rolf Sigrist
Publikováno v:
Helvetica Chimica Acta. 93:1545-1567
The oxidation of 1-(3,8-dimethylazulen-1-yl)alkan-1-ones 1 with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (=4,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,2-dicarbonitrile; DDQ) in acetone/H2O mixtures at room temperature does not only lead to the corre
Autor:
Rolf Sigrist, Hans-Jürgen Hansen
Publikováno v:
Helvetica Chimica Acta. 93:1568-1582
The 1-(3-methylazulen-1-yl)alkan-1-ones, when oxidized with excess 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (=4,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,2-dicarbonitrile; DDQ) in aqueous acetone in the presence of 1-(3-demethylazulen-1-yl)alkan-1-o
Publikováno v:
Helvetica Chimica Acta. 81:2201-2217
The reaction of guaiazulene (4) and dimethyl acetylenedicarboxylate (ADM) in tetralin or toluene, catalyzed by 5 mol-% of trifluoroacetic acid (TFA) at ambient temperature, leads to the formation of the corresponding heptalene-4,5-dicarboxylate 6 and
Publikováno v:
Helvetica Chimica Acta. 78:1408-1418
It is shown that the 2-(hydroxymethyl)-1-methylazulenes 6 are being oxidized by activated MnO2 in CH2Cl2 at room temperature to the corresponding azulene-1,2-dicarbaldehydes 7 (Scheme 2). Extension of the MnO2 oxidation reaction to 1-methyl- and/or 3
Publikováno v:
ChemInform. 26
It is shown that the 2-(hydroxymethyl)-1-methylazulenes 6 are being oxidized by activated MnO2 in CH2Cl2 at room temperature to the corresponding azulene-1,2-dicarbaldehydes 7 (Scheme 2). Extension of the MnO2 oxidation reaction to 1-methyl- and/or 3
Publikováno v:
ChemInform. 30
Autor:
Rolf Sigrist, HansJürgen Hansen
Publikováno v:
Helvetica Chimica Acta; Aug2010, Vol. 93 Issue 8, p1545-1567, 23p
Autor:
Rolf Sigrist, HansJürgen Hansen
Publikováno v:
Helvetica Chimica Acta; Aug2010, Vol. 93 Issue 8, p1568-1582, 15p