Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Rolf E. Bühler"'
Publikováno v:
The Journal of Physical Chemistry A. 107:11361-11370
We have previously shown that, in the case of extremely short lived chlorocarbon anions (of CCl 4 , CFCl 3 ) in liquid MCH solutions, one observes the formation and decay of the solvent separated ion pairs (R + ∥Cl - ) s o l v , instead of the gemi
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https://explore.openaire.eu/search/publication?articleId=doi_________::ea2d2e67093354c42aead4b6ed3c1dbe
https://doi.org/10.1021/jp030481j
https://doi.org/10.1021/jp030481j
Autor:
Rolf E. Bühler, Murat A. Quadir
Publikováno v:
The Journal of Physical Chemistry A. 107:11354-11360
In the context of studies on the influence of the anion lifetime on the geminate ion kinetics, 1,1,1,2- and 1,1,2,2-tetrachloroethane (1112-Tetra and 1122-Tetra) were studied as solutes in liquid m...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4a9651463c028b1b9dffe35144f8c70b
https://doi.org/10.1021/jp030480r
https://doi.org/10.1021/jp030480r
Autor:
Rolf E. Bühler
Publikováno v:
Radiation Physics and Chemistry. 60:323-329
We have previously shown that in the case of extremely short-lived halocarbon anions RCl − (like CCl 4 − or CFCl 3 − ), one observes the decay of the solvent-separated ion pairs (R + ||Cl − ) instead of the geminate ion recombination between
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c6154cbe2f01e95b80bebd398ed92c1d
https://doi.org/10.1016/s0969-806x(00)00370-4
https://doi.org/10.1016/s0969-806x(00)00370-4
Autor:
Murat A. Quadir, Rolf E. Bühler
Publikováno v:
The Journal of Physical Chemistry A. 104:2634-2640
The radical cation of quadricyclane (Q) was studied by pulse radiolysis at 133 K with methylcyclohexane (MCH) as solvent, saturated with N2O. The known solvent radical cations, MCH+ and its precursor M+*, are expected to produce Q+ by charge transfer
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ea0b53c6c4bf79bf0a11b9d723a3ca18
https://doi.org/10.1021/jp993707k
https://doi.org/10.1021/jp993707k
Publikováno v:
The Journal of Physical Chemistry A. 103:4986-4992
The chloroform anion in liquid methylcyclohexane (MCH) fragments during the time scale of geminate ion recombination (143 K ≤ T ≤ 193 K). Its lifetime can only be determined if the geminate ion kinetics can be calculated. The t-0.6 semiempirical
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https://explore.openaire.eu/search/publication?articleId=doi_________::f388738f657d49a195b85dd8bbd16d9e
https://doi.org/10.1021/jp984760w
https://doi.org/10.1021/jp984760w
Autor:
Rolf E. Bühler
Publikováno v:
Research on Chemical Intermediates. 25:259-274
The t -0.6 rate law by van den Ende et al. (Radiat. Phys. Chem. 22, 55 1984) is one of several methods to describe the kinetics of geminate ion recombination. Due to its simplicity it is a very powerful tool to study geminate ion mechanisms. Complica
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https://doi.org/10.1163/156856799x00446
https://doi.org/10.1163/156856799x00446
Autor:
Thomas Nauser, Rolf E. Bühler
Publikováno v:
J. Chem. Soc., Faraday Trans.. 90:3651-3656
The reactions of cloud water with transition-metal ions may be studies using pivalic acid as buffer and ˙OH scavenger. Commonly used phosphate buffers form strong complexes that may have an important effect on reaction kinetics. Low solubility produ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2cd9d29fe0f7c6afa38ad5eca2342f08
https://doi.org/10.1039/ft9949003651
https://doi.org/10.1039/ft9949003651
Publikováno v:
Berichte der Bunsengesellschaft für physikalische Chemie. 97:762-771
The catalytic decay of O2− radicals due to Cu+ and Cu2+ ions in O2 saturated solutions of low ionic strength was studied by pulse radiolysis and computer simulation of the entire reaction mechanism. Phosphate was used as buffer and formate was used
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https://doi.org/10.1002/bbpc.19930970604
https://doi.org/10.1002/bbpc.19930970604
Autor:
Rolf E. Bühler
Publikováno v:
The Carbon - Halogen Bond (1973)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::615d10dfcfafb2aa6a547e5abe3b4bd6
https://doi.org/10.1002/9780470771280.ch12
https://doi.org/10.1002/9780470771280.ch12
Publikováno v:
Berichte der Bunsengesellschaft für physikalische Chemie. 96:1448-1454
The application of tert-butanol as an OH scavenger in aqueous, oxygenated solutions was studied by pulse radiolysis and computer simulation of the entire reaction mechanism. In such systems, the initially produced tert-butanol radical (· Rtb) reacts
Externí odkaz:
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https://doi.org/10.1002/bbpc.19920961019
https://doi.org/10.1002/bbpc.19920961019