Zobrazeno 1 - 10
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pro vyhledávání: '"Roger M. G. Roberts"'
Autor:
Roger M. G. Roberts
Publikováno v:
Journal of Organometallic Chemistry. 691:4926-4930
A variety of methods have been used in the synthesis of amino-substituted (η6-arene)(η5-cyclopentadienyl) iron(II) complexes. Conventional thermal ligand exchange of 2-fluoroaniline with ferrocene in the presence of Devarda’s alloy gave an Ullman
Autor:
Roger M. G. Roberts
Publikováno v:
Journal of Organometallic Chemistry. 691:2641-2647
A series of reactions have been used to introduce oxygen substituents into (η-arene)(η-cyclopentadienyl) iron (II) complexes. Photochemical ligand exchange led to the formation of the first recorded trioxygenated complex as well as mono- and di-oxy
Autor:
Dominic A. Davies, Udo Dörfler, Roger M. G. Roberts, Jack Silver, Bernd Wrackmeyer, Max Herberhold
Publikováno v:
Journal of Organometallic Chemistry. 590:71-76
The Mossbauer spectroscopic parameters of three dibromoboryl ferrocenes and of a related dichloroboryl ferrocene are reported. The results are discussed in relation to the known crystal structures, the Mossbauer parameters and the correlation of the
Autor:
Emma Johnsen, Roger M. G. Roberts
Publikováno v:
Journal of Organometallic Chemistry. 544:197-205
[(η-Substituted arene)(η-cyclopentadienyl)Fe][PF6] complexes with amino acid side chains on the arene ring have been prepared by reaction of [(η-haloarene)(η-cyclopentadienyl)Fe][PF6] complexes with amino acids and amino acid esters under various
Publikováno v:
Journal of Organometallic Chemistry. 542:99-103
Microwave-mediated synthesis of [(η-arene)(CO)3Mn](PF6) complexes are reported. Reaction times are reduced from several hours by conventional methods to a few minutes using an unmodified domestic microwave oven. The synthesis of a bis complexed trip
Publikováno v:
Journal of Organometallic Chemistry. 474:133-141
The preparations are described of a series of mono and disubstituted derivatives of [(η-arene) (η-cyclopentadienyl)Fe[[PF6] complexes in which a range of indole-related substituents is bonded to the arene moiety via nitrogen. The preparations invol
Publikováno v:
J. Chem. Soc., Perkin Trans. 1. :197-201
A study has been made of the relative merits of a range of decomplexation reagents in the demetallation of [(η-arene)(η-cyclopentadienyl)Fe][PF6] salts. 1, 8-Phenanthroline gave good yields of the free ligand when simple arene complexes were used b
Autor:
J. R. Miller, Andrew Houlton, Roger M. G. Roberts, Jack Silver, Mustafa T. Ahmet, Richard A. Brown
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 49:1616-1619
1, 1'-Bis(diphenylphosphino)-3,3'-bis(trimethylsilyl)ferrocene acts as a bidentate ligand when reacted with CoCl 2 , producing a tetrahedral P 2 Cl 2 coordination sphere that is significantly distorted. The influence of the trimethylsilyl groups in t
Publikováno v:
Journal of Organometallic Chemistry. 456:107-111
The 13C NMR chemical shifts (δ) for azaferrocenes, phosphaferrocenes and their precursor ligands have been used to determine coordination shifts, Δδ ( = δcomplex −δligand) for the complexes. For azaferrocenes, Δδ values were similar to that
Publikováno v:
J. Chem. Soc., Dalton Trans.. :1519-1523
A series of [Fe(η-C5H4X)(η-C6H7–nXn)](X = H or Me, n= 0–6) complexes has been prepared. A detailed analysis of their 13C NMR spectra is presented, the assignments being confirmed using distortionless enhancement by polarisation transfer (DEPT)