Zobrazeno 1 - 10
of 104
pro vyhledávání: '"Roger L. Clough"'
Autor:
Roger L. Clough, Kenneth T. Gillen
Publikováno v:
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 444:135-138
In the NIMB article published by Khelidj and co-authors in 2005, they criticized one of our papers published in 1985 by stating that our radiation dose rate modeling of a PVC material predicted an infinite lifetime at low dose rates which totally ign
Publikováno v:
Polymer Degradation and Stability. 98:2452-2465
Nylon 6.6 containing 13C isotopic labels at specific positions along the macromolecular backbone has been subjected to extensive thermal-oxidative aging at 138 °C for time periods up to 243 days. In complementary experiments, unlabeled Nylon 6.6 was
Autor:
Roger L. Clough, Jonell Nicole Smith, Gregory Von White Ii, James Anthony Ohlhausen, Robert Bernstein, James Michael Hochrein
Publikováno v:
Polymer Degradation and Stability. 97:1396-1404
Oxidation of organic materials typically results in the outgassing of degradation compounds. The most abundant outgassing thermal-oxidative degradation species of nylon 6.6 are known to be carbon dioxide (CO2) and ammonia (NH3). By performing acceler
Autor:
Roger L. Clough, Adriane Nadine Irwin, Dora Kay Derzon, James Michael Hochrein, Sara B. Klamo, Steven M. Thornberg, Robert Bernstein
Publikováno v:
Polymer Degradation and Stability. 93:854-870
PP samples, in which the three unique carbon atom positions along the chain were selectively labeled with C-13, have been subjected to γ-irradiation in the presence of oxygen, and the resulting organic volatile products analyzed by GC/MS. The isotop
Autor:
Roger L. Clough, Steven M. Thornberg, M. Kathleen Alam, Daniel M. Mowery, Robert Bernstein, Dora Kay Derzon, James Michael Hochrein, Roger A. Assink, Adriane Nadine Irwin, Sara B. Klamo
Publikováno v:
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 265:8-17
In an effort to shed additional light on the chemical mechanisms underlying the radiation–oxidation of polypropylene (PP), we are using samples having selective ^(13)C isotopic labeling at the three unique sites within the macromolecular structure.
Autor:
Roger L. Clough, Roger A. Assink, Steven M. Thornberg, James Michael Hochrein, Jason R. Brown, Adriane Nadine Irwin, Sara B. Klamo, Robert Bernstein, Dora Kay Derzon
Publikováno v:
Polymer Degradation and Stability. 92:2076-2094
Making use of polypropylene samples that are selectively labeled with carbon-13 at each of the three unique positions within the repeating unit, we are conducting mass spectral analyses of the volatile organic oxidation products that are produced whe
Autor:
Daniel M. Mowery, Sara B. Klamo, Roger A. Assink, Roger L. Clough, Dora Kay Derzon, Robert Bernstein
Publikováno v:
Radiation Physics and Chemistry. 76:864-878
Polypropylene samples, in which the three different carbon atoms along the chain were selectively labeled with carbon-13, were subjected to radiation under inert and air atmospheres, and to post-irradiation exposure in air at various temperatures. By
Publikováno v:
Macromolecules. 40:3615-3623
Oxidatively degraded polypropylene (PP) samples, with selective 13C labeling of the three carbon sites on the PP chain (tertiary, secondary, and methyl carbons), have been analyzed with a suite of one- and two-dimensional solid-state 13C nuclear magn
Autor:
Steven M. Thornberg, Dora Kay Derzon, Roger L. Clough, Sara B. Klamo, Robert Bernstein, Adriane Nadine Irwin
Publikováno v:
Polymer Degradation and Stability. 92:94-102
Using a set of three isotactic polypropylene samples that had been individually labeled with carbon-13 at each of the three positions in the monomer unit, we conducted experiments to determine the position of origin of carbon monoxide and carbon diox
Publikováno v:
Polymer Degradation and Stability. 91:2146-2156
Long-term accelerated aging studies (up to 7 years of aging) were conducted on four typical EPR materials used as cable insulation in nuclear power plant safety applications with the goal of establishing lifetime estimates at typical aging conditions