Tuning photochemistry:substituent effects on πσ* state mediated bond fission in thioanisoles

Autor: Wenge, Andreas M, Karsili, Tolga N V, Rodríguez, Javier Diaz, Cotterell, Michael I, Marchetti, Barbara, Dixon, Richard N, Ashfold, Michael N R

Publikováno v: Wenge, A M, Karsili, T N V, Rodríguez, J D, Cotterell, M I, Marchetti, B, Dixon, R N & Ashfold, M N R 2015, ' Tuning photochemistry : substituent effects on πσ* state mediated bond fission in thioanisoles ', Physical Chemistry Chemical Physics, vol. 17, no. 25, pp. 16246-56 . https://doi.org/10.1039/c5cp01660f

We report a combination of experimental (velocity map imaging measurements of the methyl (Me) radical products) and ab initio electronic structure studies that explore the influence of substituents (Y) on the dynamics of S-Me bond fission following e

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https://hdl.handle.net/1983/b9393ed3-814e-4352-ab8b-176b8eeec61f