Zobrazeno 1 - 10
of 64
pro vyhledávání: '"Rodney J. Geue"'
Autor:
A. David Rae, Alan M. Sargeson, Trevor W. Hambley, David C. R. Hockless, Rodney J. Geue, Kylie N. Brown
Publikováno v:
Organic & Biomolecular Chemistry. 1:1598-1608
The racemic C3 hexadentate cage complex, [Pt(Me5-tricosatrieneN6)]Cl4 (1,5,9,13,20-pentamethyl-3,7,11,15,18,22-hexaazabicyclo[7.7.7]tricosa-3,14,18-triene)platinum(IV) tetrachloride), was synthesised stereospecifically and regiospecifically from a re
Autor:
Kaspar Hegetschweiler, Alan M. Sargeson, Jeffrey Harmer, Irmgard Buder, Walter Frank, Anja Zimmer, Vera Reiland, Arthur Schweiger, Oliver Maas, Rodney J. Geue, G. Schwitzgebel
Publikováno v:
Scopus-Elsevier
The protonation and metal complex formation of the branched pentaamine ligand 2,2,6,6-tetrakis(aminomethyl)-4-azaheptane (ditame, L) with CoII, CoIII, NII, CuII, ZnII, and CDII have been studied. The crystal structures of [Ni(ditame)(EtOH)] Br2, [CO2
Autor:
David C. R. Hockless, Alexia M. T. Bygott, Kenneth J. Haller, Rodney J. Geue, Alan M. Sargeson, A. David Rae, Stephen F. Ralph
Publikováno v:
Acta Crystallographica Section B Structural Science. 55:380-388
The crystal structures of (1,5,9,13,20-pentamethyl-3,7,11,15,18,22-hexaazabicyclo[7.7.7]tricosane-κ6 N,N′,N′′,N′′′,N′′′′,N′′′′′)nickel(II) diperchlorate–x(water) (x = 0.530), [Ni(C22H48N6)](ClO4)2.0.530H2O, and (1,5,9
Autor:
C. Jin Qin, W. Gregory Jackson, Rodney J. Geue, Alan M. Sargeson, Birgit Fabius, Rita G. Hazell, Finn K. Larsen
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :3961-3972
A facile synthesis of the tetrapodal pentaamine ligand 2,2′-dimethyl-2,2′-iminodimethylenebis(1,3-propanediamine), ditame, has been achieved and some unusual effects of its topology and preference for square pyramidal co-ordination in cobalt(III)
Autor:
K. Hegetschweiler, Rodney J. Geue, Michael Weber, A. D. Rae, Alan M. Sargeson, Volker Huch, and Anthony C. Willis
Publikováno v:
Inorganic Chemistry. 37:6136-6146
Treatment of the two CoIII-hexaamine complexes [Co(taci)2]3+ and [Co(tmca)2]3+ (taci = 1,3,5-triamino-1,3,5-trideoxy-cis-inositol, tmca = all-cis-2,4,6-trimethoxycyclohexane-1,3,5-triamine) in CH3CN with NEt3 and excess paraformaldehyde gave the corr
Autor:
Michael Weber, Alan M. Sargeson, Rodney J. Geue, Werner Angst, Kaspar Hegetschweiler, Michael Veith, Volker Huch, Anthony C. Willis, Helmut W. Schmalle, Anthony Linden, Peter Osvath
Publikováno v:
Inorganic Chemistry. 36:4121-4127
[Fe(tmca)2]3+ and [Co(tmca)2]3+ (tmca = all-cis-2,4,6-trimethoxycyclohexane-1,3,5-triamine) were prepared and characterized by elemental analyses, NMR, and FAB+ mass spectrometry and by spectroscopic methods (UV−vis). Magnetic susceptibility measur
Autor:
Alexia M. T. Bygott, Margaret M. Sheil, Anthony C. Willis, Bohdan Korybut-Daszkiewicz, Alan M. Sargeson, Patricia M. Angus, Rodney J. Geue, Albert W. H. Mau
Publikováno v:
Chemistry - A European Journal. 3:1283-1291
The template syntheses of various CoIII-hexaazaicosane-type cage complexes with aromatic substituents are described. The parent template, [Co(sen)]3+ ion {sen = 4,4′,4″-ethylidynetris(3-azabutan-1-amine)}, paraformaldehyde, a methyl aryl ketone a
Publikováno v:
Dalton Transactions. :279-281
A new template synthetic route to hexa-aza macropentacyclic cobalt(III) complexes is described together with the X-ray crystal structure of a new conformationally rigid cobalt cage complex.
Autor:
Alan M. Sargeson, Paul V. Bernhardt, Rodney J. Geue, Alexia M. T. Bygott, John R. Pladziewicz, Anthony C. Willis, Anthony J. Hendry, Bohdan Korybut-Daszkiewicz, Peter A. Lay
Publikováno v:
Inorganic Chemistry. 33:4553-4561
The cage complexes [Co{(NMe(2))(2)sar}](3+) and [Co{(NMe(2),Me)sar}](3+) (sar = sarcophagine = 3,6,10,13,16,19 hexaazabicyclo[6.6.6]icosane; (NMe(2))(2)sar 1,8-bis(dimethylamino)sarcophagine; (NMe(2),Me)sar 1-(dimethylamino)-8-methylsarcophagine) are
Publikováno v:
ChemInform. 25
A new strategy has been developed to attach N-methylpyridine and its derivatives simply and directly to the CoIII sarcophagine cage frame (sar = 3,6,10,13,16,19-hexaazsbicyclo[6.6.6]icosane).