Zobrazeno 1 - 10
of 23
pro vyhledávání: '"Rodney J. Blanch"'
Publikováno v:
Molecules, Vol 8, Iss 1, Pp 74-84 (2003)
A novel approach to cucurbituril synthesis is described where partial substitution is introduced into cucurbit[n]uril. The identification of homologues (and their substitution) in reaction mixtures is achieved by a combination of ESMS and the use of
Externí odkaz:
https://doaj.org/article/06c67b9923c8467ba3ffabd2f5df8a7e
Publikováno v:
The Journal of Organic Chemistry. 79:6978-6986
6-Carbonylcyclohexa-2,4-dienone (1) has been generated by flash vacuum thermolysis (FVT) with Ar-matrix isolation of methyl salicylate (7), 2-phenylbenzo-1,3-dioxan-4-one (8), phthalic peranhydride (9), and benzofuran-2,3-dione (11) and also by matri
Publikováno v:
The Journal of Physical Chemistry B. 107:10741-10746
This work describes the fluorescence enhancement of the probes 2,6- and 1,8-ANS via complexation with the macrocyclic host cucurbit[7]uril (Q7). The association of these two guests with the Q7 host has been studied using fluorescence, 1H NMR spectros
Publikováno v:
Journal of Inclusion Phenomena and Macrocyclic Chemistry. 43:247-250
Alkali metal cations act as templates in the synthesis ofcucurbit[n]uril, Q[n], for n = 5–8, either from a preformed oligomer precursor, ordirectly from glycoluril and formaldehyde. Q[5] has been synthesised and isolated as anunusual, water-insolub
Publikováno v:
The Journal of Organic Chemistry. 66:8094-8100
The acid-catalyzed synthesis of cucurbit[n]urils from formaldehyde and glycoluril is poorly understood. In this paper, we examine a wide range of reaction conditions that include the effects of acid type, acid concentration, reactant concentrations,
Publikováno v:
CrystEngComm. 3:230-236
We describe the insertion and physical entrapment of cis-SnCl4(OH2)2 completely inside the annulus of the cyclic methylene-linked glycoluril heptamer known as cucurbit[7]uril (Q7). This is the first endoannular metal halide–cucurbituril complex, [c
Autor:
Rodney J. Blanch, Adam McCluskey
Publikováno v:
Chemical Physics Letters. 241:116-120
Ambient light photolysis of gaseous BrCN, ClCN, and ICN results in the production of isocyanogen (NCNC) as the sole CN containing product. The flash vacuum pyrolysis of BrCN (1100°C and 10-5 mbar) generates NCNC, NCCN, HOCN, HNCO and the CN radical.
Publikováno v:
Angewandte Chemie. 114:285-287
Publikováno v:
Nano Letters. 2:147-149
The self-assembly of cucurbit[7]uril (Q7) with o-carborane (1) produces a molecular ball bearing nanostructure (2). While investigating the possible role of o-carborane as a template for the controlled synthesis of Q7, new synthetic reaction conditio
Autor:
Mark Williams, Gary D. Fallon, Colin L. Raston, Rana Kaddour, Margaret G Gardiner, Rodney J. Blanch
Publikováno v:
Angewandte Chemie International Edition in English. 36:504-506