Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Rodney H. White"'
Autor:
Rodney H. White, Neil S. Isaacs, David J. Young, Stephen D. Hiscock, Rodney E. Sue, Malcolm D. King
Publikováno v:
The Journal of Organic Chemistry. 60:7166-7169
Allylic sulfinic acids have been prepared by cleavage of trialkyltin allylic sulfinates with trifluoroacetic acid (TFA). Allylsulfinic acid prepared in this way could be trapped as the sodium salt or observed by NMR and UV spectroscopy to undergo spo
Publikováno v:
Bioorganic & Medicinal Chemistry Letters. 5:1869-1874
The p-hydroxyphenethyl halides 1(b-d) possess the minimum structural requirements for alkylating DNA with Ar-3′ participation and exhibit in vitro cytotoxicity and DNA alkylating ability/sequence selectivity which is diminished relative to more fun
Publikováno v:
ChemInform. 25
The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.
Publikováno v:
ChemInform. 28
Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal desulfination with allylic rearrangement to yield the corresponding allylic
Autor:
Phuc Van Le, Fabienne Lacrampe, Justin Anthony Ripper, Ronald J. Quinn, George Nikolakopoulos, Rodney H. White, Ian D. Jenkins, Lilian Alcaraz, Priscila de Almeida Leone
Publikováno v:
The Journal of organic chemistry. 74(3)
Inspired by the novel spiro structures of a number of bioactive natural products such as the histrionicotoxins, a series of novel spiro scaffolds have been designed and robust syntheses developed. The scaffolds are ready-to-use building blocks and ca
Publikováno v:
Bioorganic & Medicinal Chemistry Letters. 5:2931
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :1797
The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.
Publikováno v:
ResearcherID
Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal desulfination with allylic rearrangement to yield the corresponding allylic
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