Zobrazeno 1 - 10
of 26
pro vyhledávání: '"Rocco Paciello"'
Autor:
Niels Lichtenberger, Maximilian Menche, Katharina S. L. Rück, Rocco Paciello, Ansgar Schäfer, Peter Comba, A. Stephen K. Hashmi, Thomas Schaub
Publikováno v:
Organometallics. 41:1184-1196
Autor:
Duanyang Kong, Qiqige Qiqige, Wesley McNutt, Rocco Paciello, Ansgar Schäfer, Mathias Schelwies, Rylan J. Lundgren
Publikováno v:
Angewandte Chemie. 134
The transition metal catalyzed hydrogenation of alkenes is a well-developed technology used on lab scale as well as on large scales in the chemical industry. Site- and chemoselective mono-hydrogenations of polarized conjugated dienes remain challengi
Autor:
Ansgar Schäfer, Daniel J. Tindall, Rocco Paciello, A. Stephen K. Hashmi, Frank Rominger, Thomas Schaub, Peter Comba, Mathias Schelwies, Maximilian Menche
Publikováno v:
Inorganic Chemistry. 59:5099-5115
The complex Ru-MACHO has been previously shown to undergo uncontrolled degradation subsequent to base-induced dehydrochlorination in the absence of a substrate. In this study, we report that stabil...
Autor:
Tamal Ghosh, A. Stephen K. Hashmi, Katharina Rück, Ansgar Schäfer, Rocco Paciello, Saskia Krieg, Sara Sabater, Thomas Schaub, Maximilian Menche, Peter Comba
Publikováno v:
Organometallics. 39:870-880
The carbonylation of alcohols represents a straightforward and atom-efficient methodology for the preparation of carboxylic acids. It is desirable to perform these reactions under precious metal-fr...
Autor:
Kohei Sekine, Robert Konrath, Rocco Paciello, A. Stephen K. Hashmi, Ivana Jevtovikj, Thomas Schaub
Publikováno v:
Green Chemistry. 22:6464-6470
The direct access to dimethoxymethane (DMM) from CO2/H2 in MeOH is an attractive approach, but more active, selective, and robust catalyst systems are still desirable for an application of this system. Herein, we present the performance enhancing eff
Palladium-Catalyzed Low Pressure Carbonylation of Allylic Alcohols by Catalytic Anhydride Activation
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 27(36)
A direct carbonylation of allylic alcohols has been realized for the first time with high catalyst activity at low pressure of CO (10 bar). The procedure is described in detail for the carbonylation of E-nerolidol, an important step in a new BASF-rou
Publikováno v:
Applied Homogeneous Catalysis with Organometallic Compounds
Publikováno v:
Catalysis Today. 281:379-386
We have discovered a simple procedure for an industrially applicable alternative synthesis of sodium acrylate via the catalytic carboxylation of ethylene with CO 2 . We identified tert -butoxide as suitable base in this catalytic transformation, whic
Autor:
Thomas Schaub, Rocco Paciello, Núria Huguet, Anna-Corina Schmidt, Simone Manzini, Alban Cadu, Oliver Trapp
Publikováno v:
ChemCatChem. 9:2269-2274
The Pd-catalysed synthesis of sodium acrylate from ethylene and CO2 in the presence of alcoholate bases has been improved significantly. We used amide solvents such as N-cyclohexylpyrrolidone or N,N-dibutylformamide to achieve turnover numbers greate
Publikováno v:
The Journal of organic chemistry. 84(8)
Industrial–academic collaborations are broadly used for the development of new industrial processes. To achieve a strong and deep collaboration in the field of homogeneous catalysis, BASF and the Heidelberg University have been running the Catalysi