Zobrazeno 1 - 10
of 23
pro vyhledávání: '"Rocco A, Paciello"'
Autor:
Daniel J, Tindall, Maximilian, Menche, Mathias, Schelwies, Rocco A, Paciello, Ansgar, Schäfer, Peter, Comba, Frank, Rominger, A Stephen K, Hashmi, Thomas, Schaub
Publikováno v:
Inorganic chemistry. 59(7)
The complex Ru-MACHO has been previously shown to undergo uncontrolled degradation subsequent to base-induced dehydrochlorination in the absence of a substrate. In this study, we report that stabilization of the dehydrochlorinated Ru-MACHO with phosp
Autor:
Rocco A. Paciello
Publikováno v:
Applied Homogeneous Catalysis with Organometallic Compounds
Publikováno v:
ACS Catalysis. 7:6162-6169
A series of P-chirogenic Xantphos ligands and related diaryl ether diphosphines have been synthesized by a modification of the well-established Juge method. The approach consists of the in situ deboranation of the chiral ephedrine-based phosphinite b
Autor:
Dirk Michalik, Armin Börner, Rocco Dr. Paciello, Mandy-Nicole Birkholz, Ivan A. Shuklov, Natalia V. Dubrovina
Publikováno v:
Advanced Synthesis & Catalysis. 349:2183-2187
We herein describe the beneficial effect of fluorinated alcohols on asymmetric hydrogenation using chiral self-assembling rhodium complexes. Previously, the application of these catalysts has been hampered by low reaction rates in non-polar solvents,
Autor:
Natalia V. Dubrovina, Christoph Waloch, Bernhard Breit, Ivan A. Shuklov, Rocco Dr. Paciello, Mandy-Nicole Birkholz, Jens Holz, Armin Börner
Publikováno v:
Tetrahedron: Asymmetry. 18:2055-2060
New chiral phospholanes were prepared by coupling of bromo-substituted heterocycles with the enantiopure, building block (2 R ,5 R )-2,5-dimethyl-1-chlorophospholane. Some of the new phosphine ligands have the potential for self-assembling via hydrog
Publikováno v:
Macromolecules. 26:4742-4747
Ring-opening metathesis polymerization (ROMP) of exo,exo-5,6-bis(methoxymethyl)-1-oxabicyclo[2.2.1]hept-2-ene (3) catalyzed by Ru II (H 2 O) 6 (tos) 2 (tos= p-toluenesulfonate) (1) in the presence of terminal acyclic olefins such as 3-buten-1-ol and
Autor:
Rocco Dr. Paciello, Christoph Jäkel
Publikováno v:
Asymmetric Catalysis on Industrial Scale: Challenges, Approaches and Solutions, Second Edition
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c638be9145c4a35226d124436e38f181
https://doi.org/10.1002/9783527630639.ch11
https://doi.org/10.1002/9783527630639.ch11
Autor:
Ivan A. Shuklov, Mandy-Nicole Birkholz, Armin Boerner, Rocco Dr. Paciello, Natalia V. Dubrovina, Dirk Michalik
Publikováno v:
ChemInform. 39
Autor:
Dieter W. Marz, Roland A. Fischer, Wolfgang A. Herrmann, Eberhardt Herdtweck, Georg Weichselbaumer, Jun Okuda, Rocco A. Paciello
Publikováno v:
Organometallics. 9:489-496
Imido complexes of heptavalent rhenium have been synthesized by three different routes: (i) aminolysis of the half-sandwich complex ({eta}{sup 5}-C{sub 5}Me{sub 5})ReCl{sub 4} (1) (Me = CH{sub 3}) with primary amines gives the imidoderivatives ({eta}
Publikováno v:
Scopus-Elsevier
Reaction of [Fe(acac) 2 ] x (aca=η 2 -acetylacetonate) with LiCp* (Cp*=η 5 -pentamethylcyclopentadienyl) in the presence of PMe 3 or PMe 3 or DMPE (DMPE=Me 2 PCH 2 CH 2 PMe 2 ) yields Cp*LFe(acac) (L=PMe 3 (1), η 1 -DMPE (2). Compounds 1 and 2 can