Zobrazeno 1 - 10
of 106
pro vyhledávání: '"Robin G. Hicks"'
Publikováno v:
ACS Omega, Vol 7, Iss 6, Pp 5197-5205 (2022)
Externí odkaz:
https://doaj.org/article/8a8e1de9e47249c4b75d6e783b04e42f
Publikováno v:
Organic & Biomolecular Chemistry. 18:5838-5842
Reactions of indigo with quinones in the presence of sodium hydride leads unexpectedly to products containing two indigo subunits; one indigo is featured in a cis configuration and fused via its indole nitrogen atoms to a second indigo at the central
Publikováno v:
Dalton Transactions. 48:12674-12683
A series of palladium(II) complexes containing a redox-active, tridentate verdazyl ligand of general formula (verdazyl)PdL (L = Cl, CH3CN) are synthesized. The tetrazine core of tridentate verdazyl ligand 5 is flanked by two pyridyl groups, creating
Publikováno v:
Dalton Transactions. 46:12636-12644
The synthesis and ligand-centered redox chemistry of palladium complexes bearing two potentially bidentate verdazyl ligands is explored. Reaction of 1,5-diisopropyl-3-pyridin-2-yl-6-oxoverdazyl radical 1 with Pd(NCMe)4·2BF4 gives a complex containin
Publikováno v:
The Journal of Physical Chemistry A. 120:7569-7576
The protoisomerization (isomerization induced by protonation) mechanisms of indigo as well as indigo di- and monoimine derivatives were investigated using computational chemistry. Both density functional theory (M06-2X) and wave function theory (GMC-
Publikováno v:
Inorganic Chemistry. 52:10912-10919
Reactions of Nindigo-BF2 complexes with Pd(hfac)2 produced mixed complexes with Nindigo binding to both a BF2 and a Pd(hfac) unit. These complexes are the first in which the Nindigo ligand binds two different substrates, and provide a conceptual link
Publikováno v:
Inorganic Chemistry. 52:8053-8066
The electronic structures of (LX)2Ru(Vd)Ru(LX)2 complexes (Vd = 1,5-diisopropyl-3-(4,6-dimethyl-2-pyrimidinyl)-6-oxoverdazyl radical; LX = acac (acetylacetonate) or hfac (hexafluoroacetylacetonate)) in multiple charge states have been investigated ex
Autor:
Graeme Nawn, Simon R. Oakley, Marek B. Majewski, Brian O. Patrick, Robin G. Hicks, Robert McDonald
Publikováno v:
Chem. Sci.. 4:612-621
Reactions of indigo-N,N′-diarylimine (‘Nindigo’) derivatives with BF3·Et2O give mono- or bis-BF2 chelate complexes 2 or 3 respectively. The product distribution between 2 and 3 is sensitive to the auxiliary base and solvent. Although the bis-B
Autor:
Michael J. Ferguson, Brian O. Patrick, Robin G. Hicks, Robert McDonald, Kevin J. Anderson, Joe B. Gilroy
Publikováno v:
Inorganica Chimica Acta. 374:480-488
Reactions of ZnCl2 with tridentate ligands based either on a 2,2′-bipyridine-substituted verdazyl radical (1) or a 2,6-pyridine-linked verdazyl diradical (2) give trigonal bipyramidal complexes 1·ZnCl2 and 2·ZnCl2, respectively in which the Zn–
Publikováno v:
J. Mater. Chem.. 21:1523-1530
The synthesis, structures, and magnetic properties of several Pd(II) and Pt(II) complexes of verdazyl radicals are presented. Reactions of bidentate verdazyl radicals with (RCN)2MCl2 (R = Me or Ph; M = Pd or Pt) produced square planar (verdazyl)MCl2