Zobrazeno 1 - 10
of 83
pro vyhledávání: '"Roberto Pattacini"'
Publikováno v:
Dalton Transactions. 44:16242-16246
Four Au-(μ-phosphinite)-In units assemble to form an unprecedented Au2In2 12-membered metallacycle which intersects at the In centres an 8-membered ring containing two In-μ-phosphinate linkages, resulting in a tricyclic structure. Thermal treatment
Autor:
Christophe Fliedel, Alessio Ghisolfi, Pierre Braunstein, Aurore Thibon, Kirill Yu. Monakhov, Roberto Pattacini, Vitor Rosa
Publikováno v:
Chemistry-An Asian Journal
Chemistry-An Asian Journal, Wiley-VCH Verlag, 2013, 8 (8), pp.1795-1805. ⟨10.1002/asia.201300687⟩
Chemistry-An Asian Journal, Wiley-VCH Verlag, 2013, 8 (8), pp.1795-1805. ⟨10.1002/asia.201300687⟩
The coordination chemistry of the DPPA-type functional phosphine bis(diphenylphosphino)(N-thioether)amine N(PPh2)2(CH2)3SMe () and its monosulfide derivative, (Ph2P)N{P(S)Ph2}(CH2)3SMe (1·S), towards Ni(II) precursors has been investigated. The crys
Autor:
Pierre Braunstein, Roberto Pattacini, Robert P. Tooze, Susana Conde-Guadano, Kirill Yu. Monakhov, Martin J. Hanton, Andreas A. Danopoulos, Vincent Robert
Publikováno v:
Organometallics. 32:1842-1850
The synthesis and full characterization of the unprecedented open-shell Cr(II) benzyl organometallic complexes [Cr(NHC)2(benzyl)2] (2) and [Cr(NHC*)(benzyl)2] (3) (NHC = N,N′-diisopropylimidazol-2-ylidene; NHC* = N,N′-bis(2,6-diisopropylphenyl)im
Publikováno v:
Journal of Cluster Science. 24:11-16
The 68-electrons, phosphane-substituted, osmium selenido-carbonyl cluster [Os4Se3(CO)10(dppm)] (cluster 3; dppm = bis(diphenylphosphino)methane) has been obtained by reaction under mild experimental conditions between [Os3(CO)12] and the diphosphane
Autor:
Nelsi Zaccheroni, Sara Bonacchi, Matteo Calvaresi, Francesco Zerbetto, Massimiliano Delferro, Roberto Pattacini, Luca Prodi, Roberto Paolesse, Daniele Cauzzi, Corrado Di Natale, Marco Montalti, Francesca Dini
Publikováno v:
Angewandte Chemie. 124:9800-9803
We report the distinctive photophysical properties of a Cu5-core metal cluster that presents, both in solution and in the solid, temperature dependent fluorescent quantum yield and excited state lifetime in the range between -45 and +80 °C. It allow
Autor:
Andreas A. Danopoulos, Robert P. Tooze, Roberto Pattacini, Susana Conde-Guadano, Martin J. Hanton
Publikováno v:
Organometallics. 31:1643-1652
The chromium(III) complexes of the type L1CrXY (L1 = 1-(2,6-diisopropylphenyl)-3-[β-(4,7-dimethylindenyl)ethyl]-imidazol-2-ylidene, X, Y = Cl, 2a-Cl; X = Cl, Y = Me, 2a-Me; X = Cl, Y = Ph, 2a-Ph; X, Y = benzyl, 2a-Bz) and L2CrCl2 (L2 = 1-(2,6-diisop
Publikováno v:
Comptes Rendus Chimie. 15:229-236
The ligands N-(diphenylphosphino)-thiazoline-2-amine (1), N-(diphenylphosphino)thiazol-2-amine (2) and N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine 3, readily reacted with [AuCl(THT)] in dichloromethane to form the linearly coordinated complexes [A
Publikováno v:
Inorganic Chemistry. 51:1562-1568
We describe the unique structural and electronic arrangement in the heptanuclear polyiodobismuthate [Bi(7)I(24)](3-) which displays striking similarities with the Anderson-type structures found in polyoxometalates. This main group element anion is pa
Publikováno v:
Dalton Trans.. 41:379-386
The Pd(II) complex [PdCl(2)(1)] [1 = ({oxazolin-2-yl}methyl)diphenylphosphine] was obtained by the 1:1 reaction of 1 with [PdCl(2)(NCPh)(2)]. Although this neutral complex is stable in the solid-state and in solution, it reacts with the dinuclear com
Publikováno v:
Organometallics. 30:3302-3310
New Cu(I) and Ag(I) complexes containing a chelating bis(N-heterocyclic carbene) ligand, in which an aryl group acts as a spacer between the NHC donor groups, have been prepared by deprotonation of the bis-imidazolium salt 1,1′-((4,6-dimethyl-1,3-p