Zobrazeno 1 - 10
of 34
pro vyhledávání: '"Robert W. Graff"'
Autor:
Manzhou Zhu, Yi Shi, Robert W. Graff, Haifeng Gao, Daqiao Hu, Shan Jin, Wenqi Liu, Xiaofeng Wang
Publikováno v:
Nanoscale. 9:3629-3636
A robust approach is developed to prepare hyperstar polymer-Au25(SR)18 nanocomposites for catalysis. The synthesis started with atom transfer radical copolymerization of an inimer with a cyclic disulfide-containing methacrylate monomer in a microemul
Publikováno v:
Macromolecules. 49:6471-6479
This article presents the first synthesis of high-molecular-weight hyperbranched polymers (over half a million) in the homopolymerization of a polymerizable trithiocarbonate chain transfer agent (i.e., transmer). Traditional reversible addition–fra
Autor:
Yi Shi, Robert W. Graff, Haifeng Gao, Weiping Gan, Xiaofeng Wang, Hannah Naguib, Xiaosong Cao
Publikováno v:
Macromolecules. 49:5342-5349
A series of AB2-R monomers that were composed of one alkynyl group (A), two azido groups (B2), and a dangling group (R) were applied in the copper-catalyzed azide–alkyne cycloaddition (CuAAC) polymerization for synthesis of hyperbranched polymers.
Autor:
Daqiao Hu, Xiaosong Cao, Xiaofeng Wang, Ruilan Guo, Haifeng Gao, Shuangjiang Luo, Robert W. Graff, Yi Shi
Publikováno v:
Macromolecules. 49:4416-4422
Hyperbranched copolymers with segmented structures were synthesized using a chain-growth copper-catalyzed azide–alkyne cycloaddition (CuAAC) polymerization via sequential monomer addition in one pot. Three AB2-type monomers that contained one alkyn
Publikováno v:
Macromolecules. 49:760-766
We present the first one-pot one-batch synthesis of hyperbranched polymers with over a million molecular weight and low polydispersity in the copper-catalyzed alkyne–azide cycloaddition (CuAAC) polymerization of AB2 monomer. In contrast to the trad
Autor:
Xiaosong Cao, Yi Shi, Weiping Gan, Robert W. Graff, Daqiao Hu, Xiaofeng Wang, Lei Zou, Haifeng Gao
Publikováno v:
Polymer Chemistry. 7:5512-5517
A tetrafunctional AB3 monomer that was composed of one alkynyl group, three azido groups and one acetal linker was used in the one-pot copper-catalyzed azide–alkyne cycloaddition (CuAAC) polymerization for producing acid-degradable hyperbranched po
Publikováno v:
Macromolecular Rapid Communications. 36:2076-2082
The effect of branching point structures and densities is studied between azido-containing hyperbranched polymers and cross-linked nanogels on their loading efficiency of alkynyl-containing dendron molecules. Hyperbranched polymers that contained "T"
Publikováno v:
Polymer. 72:361-367
Hybrid magnetic nanoparticles (MNPs) with well-defined core-shell structure, pH-tunable interfacial activity and strong magnetic responsiveness were developed as recyclable stabilizers for oil–water separation. The Fe3O4 magnetic core was synthesiz
Publikováno v:
Angewandte Chemie International Edition. 54:7631-7635
Hyperbranched polymers are important soft nanomaterials but robust synthetic methods with which the polymer structures can be easily controlled have rarely been reported. For the first time, we present a one-pot one-batch synthesis of polytriazole-ba
Publikováno v:
Macromolecules. 48:2118-2126
A synthetic method was successfully developed to produce structurally defined hyperbranched polymers using confined micellar space in microemulsion to regulate atom transfer radical polymerization (ATRP) of inimers. Systematic exploration of experime