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pro vyhledávání: '"Robert W Lencki"'
Autor:
R. John Craven, Robert W. Lencki
Publikováno v:
Journal of the American Oil Chemists' Society. 90:1509-1516
Negative pressure effects appear to play an important role during crystallization of complex TAG mixtures such as cocoa butter. Crystallization conditions influence the final macroscopic sample density and the resulting gaseous phase void structure.
Autor:
Robert W. Lencki, R. John Craven
Publikováno v:
Chemical Reviews. 113:7402-7420
Autor:
Robert W. Lencki, R. John Craven
Publikováno v:
Lipid Technology. 24:204-207
Unit-cell stereochemistry for triacylglycerols in β′ (beta prime here and throughout) and β forms has been compared using data from studies of phase behavior for enantiomeric mixtures and space group determinations. The β′ form has a unit cell
Autor:
Robert W. Lencki, R. John Craven
Publikováno v:
Crystal Growth & Design. 12:4981-4986
Under certain crystallization conditions, β-tending triacylglyerol (TAG) can form cavities within the crystal network, leading to situations where the macroscopic solid density is less than the melted liquid phase. A similar phenomenon, termed negat
Autor:
R. John Craven, Robert W. Lencki
Publikováno v:
Journal of the American Oil Chemists' Society. 89:741-744
Polymorphism strongly affects the functionality of fat and fat-containing foods. For instance, margarine in the desirable b0 form is smooth and creamy, whereas, the more stable b polymorph is associated with a grainy texture. Similarly, cocoa butter
Autor:
Robert W. Lencki, R. John Craven
Publikováno v:
Crystal Growth & Design. 11:1566-1572
Triacylglycerols (TAG) are the main component in fats and oils and a major component in many food and consumer products. These compounds are always asymmetric (about the sn-2position), while many diacid and all triacid TAG are chiral. To understand w
Autor:
R. John Craven, Robert W. Lencki
Publikováno v:
Crystal Growth & Design. 11:1723-1732
Autor:
Robert W. Lencki, R. John Craven
Publikováno v:
Journal of the American Oil Chemists' Society. 88:1113-1123
Crystallization and melting behavior, small-angle X-ray scattering, X-ray powder diffraction and infra-red absorbance were measured for nine 1,3-acyl-palmitoyl-rac-glycerols (1,3-acetoyl-, -butyroyl-, -hexanoyl-, -octanoyl-, -decanoyl-, -lauroyl, -my
Autor:
Robert W. Lencki, R. John Craven
Publikováno v:
Journal of the American Oil Chemists' Society. 88:1125-1134
Fifteen phase diagrams were prepared using data from differential scanning calorimetry analysis of binary blends of representative diacid 1,3-DAG. The behavior observed in binary phase diagrams is related to the difference in T m (ΔT m) between syst
Autor:
Robert W. Lencki, R. John Craven
Publikováno v:
Journal of the American Oil Chemists' Society. 87:1281-1291
A complete methodology (including synthesis, purification and analysis) for the preparation of 1,3-DAG is described. For a successful synthesis project, the strengths and weaknesses of each particular process should be taken into account and measures