Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Robert M. Stoop"'
Publikováno v:
Organometallics. 19:4117-4126
The five-coordinate complexes of the type [RuCl(PNNP)]PF6 (PNNP = tetradentate ligand with a P2N2 donor set) are prepared by chloride abstraction from [RuCl2(PNNP)]. A mixture of Δ-cis-β- and Λ-cis-β-[RuCl2(1a-κ4P,N,N,P)] (2a; 1a = N,N‘-bis[o-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::013b7d943b6605e1226786b71c34b8e1
https://doi.org/10.1021/om000481v
https://doi.org/10.1021/om000481v
Publikováno v:
Organometallics. 19:2844-2852
The five-coordinate fluoro complex [RuF(dppp)2]PF6 (1a) has been prepared by reacting [RuCl(dppp)2]PF6 (1b) with TlF (dppp = 1,3-bis(diphenylphosphino)propane). An X-ray investigation of 1a shows a distorted trigonal bipyramidal geometry (Y-shaped).
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bbff4c6933abcf6b4998a1783f08a7ce
https://doi.org/10.1021/om0000156
https://doi.org/10.1021/om0000156
Autor:
Lukas Hintermann, Antonio Togni, Antonio Mezzetti, Robert M. Stoop, Peter Barthazy, Michael Wörle
Publikováno v:
Helvetica Chimica Acta. 82:2448-2453
The 16-electron, five-coordinate fluoro complex [RuF(dppp)2]PF6 (1a; dppp=propane-1,3-diylbis[diphenylphosphine] smoothly reacts with 1,3-diphenylallyl bromide (=1,1′-(3-bromoprop-1-ene-1,3-diyl)bis[benzene]) in dry CDCl3 to give 1,3-diphenylallyl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cb7ef7c519a3f4cd06d6a178b28cb861
https://doi.org/10.1002/(sici)1522-2675(19991215)82:12<2448::aid-hlca2448>3.0.co
https://doi.org/10.1002/(sici)1522-2675(19991215)82:12<2448::aid-hlca2448>3.0.co
Autor:
Antonio Mezzetti, Patrick D. Setz, and Terrance Y. H. Wong, Christian Bauer, Robert M. Stoop, Michael Wörle
Publikováno v:
Organometallics. 18:5691-5700
The six-coordinate complexes trans-[RuCl2(P−P*)2] (P−P* = (S,S)-1,2-bis(1-naphthylphenylphosphino)ethane (bnpe), 2a; (S,S)-2,3-bis(diphenylphosphino)butane (chiraphos), 2b) have been prepared and structurally characterized. The X-ray studies of 2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::09ea49122204829af23a96d4737f413a
https://doi.org/10.1021/om990657x
https://doi.org/10.1021/om990657x
Publikováno v:
Organometallics. 17:668-675
The diphosphine (S,S)-Me2Si(CH2P(1-Np)(Ph))2 (1-Np = 1-naphthyl) (1), containing stereogenic P atoms, is prepared with high diastereo- and enantiomeric purity by a multistep asymmetric synthesis via its borane adduct (S,S)-Me2Si(CH2P(1-Np)(Ph)(BH3))2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9f5cc5fe543fa7d6927773cdd8dd1b98
https://doi.org/10.1021/om970539e
https://doi.org/10.1021/om970539e
Autor:
Antonio Mezzetti, Robert M. Stoop
Publikováno v:
Green Chemistry. 1:39-41
Up to 40% ee was obtained in the asymmetric epoxidation of styrene and other unfunctionalised olefins catalysed by the ruthenium(II) complex [RuCl(PNNP)]PF6 (PNNP = N,N′-{(o-diphenylphosphino)benzylidene}-(1S,2S)-diiminocyclohexane)using hydrogen p
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::273fdaac57fbf9a03531db97031d7d66
https://doi.org/10.1039/a809640f
https://doi.org/10.1039/a809640f
Publikováno v:
Chemistry - A European Journal. 10:1312-1312
Iridium complexes relevant to the catalytic enantioselective hydrogenation of 2-methyl-6-ethylphenyl-1'-methyl-2'-methoxyethylimine (MEA-imine, 1) in the Syngenta Metolachlor (3) process were prepared and characterized. Reaction of the diphosphane (S
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f64d91fe6a416dec2c0c164e714063b7
https://doi.org/10.1002/chem.200490019
https://doi.org/10.1002/chem.200490019
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