The Bent Bonds of Cubane

Autor: Robert J. Doedens, Everly B. Fleischer, Philip E. Eaton

Publikováno v: European Journal of Organic Chemistry. 2017:2627-2630

The carbon–carbon bonding in cubane is shown not to be along the C–C vectors between carbon atoms at the corners of a cube. Instead, the bonding is “bent” as seen in a new single-crystal X-ray structure of cubane at 93 K. The bent bond angles

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9bdcdfb23af4976eac69b201fea663d3
https://doi.org/10.1002/ejoc.201700427

Organo-functionalized metal–oxide clusters: synthesis and characterization of the reduced cationic species [NaVIV6O6{(OCH2CH2)2NH}6]+

Autor: M. Ishaque Khan, A. Basha, Hanbo Li, Robert J. Doedens, LaSalle Swenson, Y. Zheng

Publikováno v: Khan, MI; Zheng, Y; Li, H; Swenson, L; Basha, A; & Doedens, RJ. (2014). Organo-functionalized metal-oxide clusters: Synthesis and characterization of the reduced cationic species [NaVIV6O6{(OCH2CH2)2NH}6]+. Dalton Transactions, 43(43), 16509-16514. doi: 10.1039/c4dt02174f. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/4k22m0jz

© 2014 the Partner Organisations. A new heteropolyoxovanadium compound, [NaV6O6{(OCH2CH2)2NH}6]·(OH)0.5Cl0.5·3(H2O), was synthesized and characterized by single-crystal X-ray diffraction analysis, cyclic voltammetry, FTIR and UV-vis spectroscopy,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a6f4568a760f0ffa79dfe73987cb0153
https://doi.org/10.1039/c4dt02174f

Synthesis of the (N2)3− Radical from Y2+ and Its Protonolysis Reactivity To Form (N2H2)2− via the Y[N(SiMe3)2]3/KC8 Reduction System

Autor: Robert J. Doedens, Filipp Furche, Joseph W. Ziller, David S. Lee, William J. Evans, Ming Fang, Jefferson E. Bates

Publikováno v: Journal of the American Chemical Society. 133:3784-3787

Examination of the Y[N(SiMe(3))(2)](3)/KC(8) reduction system that allowed isolation of the (N(2))(3-) radical has led to the first evidence of Y(2+) in solution. The deep-blue solutions obtained from Y[N(SiMe(3))(2)](3) and KC(8) in THF at -35 °C u

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::998432098a9b18b6eab498d844ce4876
https://doi.org/10.1021/ja1116827

Inorganic−Organic Hybrid Materials with Novel Framework Structures: Synthesis, Structure, and Magnetic Properties of [Ni(py)4]2V10O29 and [Ni2(py)5(H2O)3]V4O12

Autor: James McNeely, Renata C. Nome, Sangita Deb, Brant Cage, Robert J. Doedens, M. Ishaque Khan

Publikováno v: Crystal Growth & Design. 9:2848-2852

Inorganic−organic hybrid materials [Ni(py)4]2V10O29 (1) and [Ni2(py)5(H2O)3]V4O12 (2) have been synthesized and characterized by infrared spectroscopy, thermogravimetry, magnetometry, and complete single crystal structure analysis. The crystal stru

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::58cda90d0d16cf5868235b70e94cd838
https://doi.org/10.1021/cg9001237

Mixed-Valence and Neutral Framework Inorganic−Organic Hybrid Materials: Synthesis, Characterization, and Magnetic Properties of [{Co(N(CH)4N)}(V2O5)2] and [{Co(N(CH)4N)}V2O6]

Autor: M. Ishaque Khan, Elizabeth Yohannes, Charles J. O'Connor, Vladimir Golub, Robert J. Doedens

Publikováno v: Chemistry of Materials. 19:4890-4895

Two inorganic−organic hybrid materials [{Co(N(CH)4N)}(V2O5)2] (1) and [{Co(N(CH)4N)}V2O6] (2) have been synthesized and characterized by FT-IR spectroscopy, thermogravimetric analysis, elemental analysis, manganometric titration, temperature-depend

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::86c61e26dfbb55003bf27c6ee1b675b9
https://doi.org/10.1021/cm071415n