Zobrazeno 1 - 10
of 99
pro vyhledávání: '"Robert G. Snyder"'
Publikováno v:
The Journal of Physical Chemistry B. 110:2378-2386
The major barrier to permeability in skin resides in the outermost layer of the epidermis, the stratum corneum (SC). The major SC lipid components are ceramides, free fatty acids, and cholesterol. Ternary mixtures containing these constituents are wi
Publikováno v:
The Journal of Physical Chemistry A. 107:9329-9334
We have studied the infrared spectra of the OH(D) hydrogen bonds from the water and NH(D) bonds from the NH2 group in the title compound as functions of deuterium concentration and temperature. Som...
Publikováno v:
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 59:671-680
Normal mode analyses are made for methyl palmitate molecule having all-trans or conformational disorders around the ester head group, in order to explain characteristic observed frequency shifts in the wagging progressive region between all-trans and
Autor:
Kechuan Tu, Richard Mendelssohn, Herbert L. Strauss, Robert G. Snyder, Michael L. Klein, Wenjun Sun
Publikováno v:
The Journal of Physical Chemistry B. 106:6273-6288
The lipid chain conformation predicted by a recent molecular dynamics simulation (MD) of the fluid and gel phases of a dipalmitoylphosphatidylcholine (DPPC) phospholipid bilayer is described in detail and, where possible,is compared to the results of
Publikováno v:
The Journal of Physical Chemistry B. 104:4229-4238
An IR study of the conformational disorder in the part of the hydrocarbon chain nearest the ester group in gel-phase lipid bilayers is presented. The infrared method for determining the conformation of the CH2−CH2 bond attached to the ester group i
Publikováno v:
The Journal of Physical Chemistry B. 104:532-537
In an investigation of methylene replacement by small heteroatom insertions the crystal structures of N,N-dioctadecylamine, (C18H37)2NH, and dihexadecyl ether, (C16H33)2O, were determined by electron crystallography and infrared spectroscopy. Crystal
Autor:
Robert G. Snyder, Douglas L. Dorset
Publikováno v:
Macromolecules. 32:8139-8144
The orthorhombic crystal packing of 15-trans-triacontene was determined from electron diffraction intensities observed from epitaxially oriented and from solution-grown samples and by infrared spectroscopy of melt-crystallized thin layers. As determi
Publikováno v:
The Journal of Physical Chemistry B. 103:10461-10468
X-ray diffraction studies of ammonium myristate and palmitate show crystals that belong to space group P21/n with the methylene groups packing in a triclinic subcell. The infrared spectra of the palmitate and stearate are similar as expected, but the
Autor:
Douglas L. Dorset, Robert G. Snyder
Publikováno v:
The Journal of Physical Chemistry B. 103:3282-3286
An equimolar combination of n-C28H58/n-C32H66/n-C36H74, crystallized from the melt, initially forms a solid solution. Electron diffraction data from the epitaxially oriented [100] projection can be used to determine its crystal structure, a pseudo n-
Publikováno v:
The Journal of Physical Chemistry B. 101:335-343
The interlamellar disorder in waxes is a major factor in determining their unique physical properties. We have measured by Raman and infrared spectroscopies the conformational disorder and chain pa...