Zobrazeno 1 - 10 of 436 pro vyhledávání: '"Robert E. Mulvey"'
1
Akademický článek
Synthesis, characterisation, and catalytic application of a soluble molecular carrier of sodium hydride activated by a substituted 4-(dimethylamino)pyridine
Autor: Peter A. Macdonald, Alan R. Kennedy, Catherine E. Weetman, Stuart D. Robertson, Robert E. Mulvey
Publikováno v: Communications Chemistry, Vol 7, Iss 1, Pp 1-7 (2024)
Abstract Recently main group compounds have stepped into the territory of precious transition metal compounds with respect to utility in the homogeneous catalysis of fundamentally important organic transformations. Inspired by the need to promote mor
Externí odkaz: https://doaj.org/article/1682ec1c57084979a25c571efefedacc
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2
Akademický článek
Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation
Autor: David R. Armstrong, Liam Balloch, Eva Hevia, Alan R. Kennedy, Robert E. Mulvey, Charles T. O'Hara, Stuart D. Robertson
Publikováno v: Beilstein Journal of Organic Chemistry, Vol 7, Iss 1, Pp 1234-1248 (2011)
Previously we reported that direct zincation of N,N-dimethylaniline by the mixed-metal zincate reagent 1 ((TMEDA)Na(TMP)(t-Bu)Zn(t-Bu)) surprisingly led to meta-metallation (zincation) of the aniline, as manifested in the crystalline complex 2 ((TMED
Externí odkaz: https://doaj.org/article/993df48448c7416290f8b1104df1f708
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3
Akademický článek
catena-Poly[sodium-μ2-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ2N:N′-sodium-bis[μ2-bis(trimethylsilyl)azanido-κ2N:N]]
Autor: Alan R. Kennedy, Robert E. Mulvey, Charles T. O'Hara, Stuart D. Robertson, Gemma M. Robertson
Publikováno v: Acta Crystallographica Section E, Vol 68, Iss 12, Pp m1468-m1468 (2012)
The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N′,N′-tetramethylethylenedi
Externí odkaz: https://doaj.org/article/9554bb7690694235a28f2e66caee49fb
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5
Structural characterization of three hydride-bridged sodium aluminate compounds
Autor: Alan R. Kennedy, Robert E. Mulvey, Michael T. Whitelaw
Publikováno v: Acta Crystallographica Section E Crystallographic Communications. 78:1217-1222
The synthesis and single-crystal structures of three hydride-bridged sodium aluminate compounds containing the utility amide HMDS [N(SiMe3)2 or C6H18NSi2] are reported. Both bis[bis(trimethylsilyl)amido-2κN]-μ-hydrido-hydrido-2κH-(N,N,N′,N′′
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bec0ff67084c89a7a0416018bc41f46e
https://doi.org/10.1107/s2056989022010738
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8
Rubidium and caesium aluminyls: synthesis, structures and reactivity in C–H bond activation of benzene
Autor: Thomas X. Gentner, Matthew J. Evans, Alan R. Kennedy, Sam E. Neale, Claire L. McMullin, Martyn P. Coles, Robert E. Mulvey
Publikováno v: Gentner, T, Evans, M, Kennedy, A, Neale, S, McMullin, C, Coles, M & Mulvey, R 2022, ' Rubidium and caesium aluminyls: synthesis, structures and reactivity in C–H bond activation of benzene ', Chemical communications (Cambridge, England), vol. 58, no. 9, pp. 1390-1393 . https://doi.org/10.1039/D1CC05379E
Expanding knowledge of low valent aluminium chemistry, rubidium and caesium aluminyls are reported to complete the group 1 (Li–Cs) set of metal aluminyls. Both compounds crystallize as a contacted dimeric pair supported by M⋯π(arene) interaction
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f706ed6e0f846c1d9631a00c4e945fd1
https://doi.org/10.1039/d1cc05379e
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