Zobrazeno 1 - 10
of 177
pro vyhledávání: '"Robert E. Huie"'
Autor:
Robert E. Huie, John T. Herron
Publikováno v:
J Res Natl Bur Stand A Phys Chem
Rate constants have been measured from 307 to 652 K for the reactions of atomic oxygen (O(3)P) with spiropentane, cyclopentane, cyclohexane, and cycloheptane. The derived Arrhenius parameters are k(sp − C(5)H(8)) = 10(13.60±0.10) exp[(−2890 ± 1
Autor:
Robert E. Huie, Gabor Merenyi, David M. Stanbury, Willem H. Koppenol, Branko Ruscic, Pedatsur Neta, David A. Armstrong, Peter Wardman, S. Steenken, Sergei V. Lymar
Publikováno v:
Pure and Applied Chemistry. 87:1139-1150
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literatur
Autor:
Gabor Merenyi, Pedatsur Neta, David M. Stanbury, David A. Armstrong, Sergei V. Lymar, Robert E. Huie, Peter Wardman, Willem H. Koppenol, Sten Steenken
Publikováno v:
BioInorganic Reaction Mechanisms, 9 (1-4)
Inorganic radicals, such as superoxide and hydroxyl, play an important role in biology. Their tendency to oxidize or to reduce other compounds has been studied by pulse radiolysis; electrode potentials can be derived when equilibrium is established w
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d2defbbf7548297f4f3afcee661094b2
http://doc.rero.ch/record/295084/files/irm-2013-0005.pdf
http://doc.rero.ch/record/295084/files/irm-2013-0005.pdf
Autor:
Robert E, Huie
Publikováno v:
Journal of Research of the National Institute of Standards and Technology
Autor:
Dianne L. Poster, Jung-Chul An, Pedatsur Neta, Robert E. Huie, Mohamad Al-Sheikhly, Joseph Silverman
Publikováno v:
Environmental Science & Technology. 40:3082-3088
Pulse radiolysis with spectrophotometric and conductometric detection was utilized to study the formation and reactions of radicals from benzene and dienes in aqueous solutions. The benzene OH adduct, *C6H6OH, reacts with O2 (k = 3 x 10(8) L mol(-1)
Publikováno v:
The Journal of Supercritical Fluids. 32:123-135
Kinetics and thermodynamics of 2-propanol dehydration in supercritical water (SCW) and the effect of density on this reaction have been investigated in a batch reactor. The studies were performed at water densities between 0.24 and 0.58 g/cm 3 and te
Autor:
Steven J. Eisenreich, Joel E. Baker, Dianne L. Poster, and Cari L. Gigliotti, Holly A. Bamford, John H. Offenberg, Robert E. Huie, Lisa A. Totten
Publikováno v:
Environmental Science & Technology. 38:1629-1632
Publikováno v:
The Journal of Physical Chemistry A. 107:7423-7428
30) L mol -1 cm -1 and 580 ) (56 ( 30) L mol -1 cm -1 . The ¥ NHCl radical undergoes self-decay and can react also with O2 to form a peroxyl radical. It is suggested that the peroxyl radical exists in equilibrium NHClO 2 ¥ / ¥ NHCl + O2 with an es
Publikováno v:
The Journal of Physical Chemistry A. 107:1964-1970
The rate and equilibrium constants for the reaction NO3• + Cl- ⇄ NO3- + Cl• in aqueous solutions were measured by pulse radiolysis. The formation and decay of the nitrate radical, NO3•, and the dichloride radical anion, Cl2•-, in irradiated
Publikováno v:
The Journal of Physical Chemistry A. 107:1333-1338
The rate constants for the reactions of OH radicals with the 1-bromopropane, 2-bromopropane, and propane were measured using the flash photolysis resonance fluorescence technique over the temperature range between 210 and 480 K. Arrhenius plots exhib