Chemistry and Biological Activity of Platinum Amidine Complexes

Autor: Roberta Bertani, Valentina Gandin, Cristina Marzano, Rino A. Michelin, Silvia Mazzega Sbovata, Paolo Sgarbossa

Publikováno v: ChemMedChem. 6:1172-1183

Platinum amidine complexes represent a new class of potential antitumor drugs that contain the imino moiety HN=C(sp(2)) bonded to the platinum center. They can be related to the iminoether derivatives, which were recently shown to be the first Pt(II)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6fe93daae7bc8306024e36cf22be4822
https://doi.org/10.1002/cmdc.201100150

The Baeyer–Villiger oxidation of ketones: A paradigm for the role of soft Lewis acidity in homogeneous catalysis

Autor: Giorgio Strukul, Rino A. Michelin, Alessandro Scarso, Paolo Sgarbossa

Publikováno v: Coordination Chemistry Reviews. 254:646-660

The Baeyer–Villiger oxidation of ketones to the corresponding esters or lactones is a valuable transformation that has been upgraded several times over the last century, from the original use of monopersulfuric acid as oxidant to more atom efficien

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6259fdf962850dad83583745e43d2527
https://doi.org/10.1016/j.ccr.2009.09.014

Synergism between flame retardant and modified layered silicate on thermal stability and fire behaviour of polyurethane nanocomposite foams

Autor: Roberta Bertani, Denis Hrelja, Alessandra Lorenzetti, Michele Modesti, Stefano Besco, Rino A. Michelin, S. Semenzato

Publikováno v: Polymer Degradation and Stability. 93:2166-2171

Synergy in flame retardancy of polyurethane foams between phosphorus-based flame retardant (aluminium phosphinate) and layered silicates has been investigated. We used pristine montmorillonite as well as ammonium modified clay (commercially available

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::60d2c74fed596e0b393aeb405d06e4b7
https://doi.org/10.1016/j.polymdegradstab.2008.08.005

Benzylamidine complexes of platinum(II) derived by nucleophilic addition of primary and secondary amines. X-ray crystal structure of trans-[PtCl2{Z-N(H)C(NHMe)CH2Ph}2]

Autor: Roberta Bertani, Rino A. Michelin, Silvia Mazzega Sbovata, Christine Marzano, Mirto Mozzon, Frazia Bettio, Franco Benetollo

Publikováno v: Inorganica Chimica Acta (Testo stamp.) 361 (2008): 3109–3116.
info:cnr-pdr/source/autori:Mazzega Sbovata S. 1, Bettio Frazia 2, Marzano Christine 2, Mozzon Mirto 1, Bertani Roberta 1, Benetollo Franco 3, Michelin Rino A. 1/titolo:Benzylamidine complexes of platinum(II) derived by nucleophilic addition of primary and secondary amines. X-ray crystal structure of trans-[PtCl2{Z-N(H)=C(NHMe)CH2Ph}2]/doi:/rivista:Inorganica Chimica Acta (Testo stamp.)/anno:2008/pagina_da:3109/pagina_a:3116/intervallo_pagine:3109–3116/volume:361

The reaction of cis - and trans -[PtCl 2 (NCCH 2 Ph) 2 ] with a 5-fold excess of MeNH 2 and Me 2 NH in CH 2 Cl 2 at −10 °C affords in high yield the bis-amidine derivatives cis - and trans -[PtCl 2 { Z -N(H) C(NHMe)CH 2 Ph} 2 ] ( 1a , 2a ) and cis

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ab410a412b393f1d665c78bfe93321d0
https://doi.org/10.1016/j.ica.2007.10.054

Synthesis, characterization and Baeyer–Villiger oxidation of ketones by the bis-cationic platinum(II) complex [Pt(μ-OH)(Pom-Pom)]2[BF4]2 [Pom-Pom=(OMe)2PCH2CH2P(OMe)2]

Autor: Rino A. Michelin, Alessandro Scarso, Paolo Sgarbossa, Erika Pizzo, Giorgio Strukul, Silvia Mazzega Sbovata, Augusto Tassan

Publikováno v: Journal of Molecular Catalysis A: Chemical. 261:202-206

The synthesis and spectroscopic characterization of the new hydroxo-bridged platinum(II) complex [P(μ-OH)(Pom-Pom)] 2 [BF 4 ] 2 ( 3 ) containing the electron-poor P–P ligand 1,2-bis(dimethoxyphosphino)ethane, (OMe) 2 PCH 2 CH 2 P(OMe) 2 (Pom-Pom),

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::44c23c3daa4f174f77777cb3be10bdc6
https://doi.org/10.1016/j.molcata.2006.08.011