Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Riki Das"'
Publikováno v:
Synthesis. 51:2515-2522
A unique approach to achieve regioselective C(3)–H olefination of isoquinolines under ruthenium-catalyzed conditions has been developed. The acetyl group of N-acetyl-1,2-dihydroisoquinoline acts as a directing group for this C–H olefination strat
Autor:
Riki Das, Manmohan Kapur
Publikováno v:
Asian Journal of Organic Chemistry. 7:1217-1235
Autor:
Manmohan Kapur, Riki Das
Publikováno v:
Asian Journal of Organic Chemistry. 7:1524-1541
Publikováno v:
European Journal of Organic Chemistry. 2017:5439-5459
Site selectivity is an inherent challenge in C–H functionalization reactions. The most intensively sought-after approaches have involved the employment of Lewis-basic coordinating groups to direct a metal to a proximal site, in the process generati
Autor:
Manmohan Kapur, Riki Das
Publikováno v:
The Journal of Organic Chemistry. 82:1114-1126
A palladium-catalyzed, ortho-selective C–H halogenation methodology is reported herein. The highlight of the work is the highly selective C(sp2)–H functionalization of benzyl nitriles in the presence of activated C(sp3)–H bond, which results in
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 26(4)
A unique approach to achieve site-selective C-H olefinations exclusively at the C-3- or C-8-positions in the quinoline framework has been developed by catalyst control. Distal C(3)-H functionalization is achieved by using palladium catalysis, whereas
Autor:
Manmohan Kapur, Riki Das
Publikováno v:
Chemistry - A European Journal. 22:16986-16990
A new class of Weinreb amides has been developed as directing groups for the ruthenium-catalysed regioselective oxidative C-H olefination. The new Weinreb amides successfully inhibit the N-O bond reductive cleavage usually associated with the cationi
Publikováno v:
Organic Letters. 15:3310-3313
A new approach for the regioselective functionalization of the C-3-position of quinolines is described. The method utilizes heteroatom guided regioselective C-3 palladation followed by arylation via transmetalation with aryl boronic acids to yield 3-
Autor:
Riki Das, Manmohan Kapur
Publikováno v:
ChemInform. 46
The ruthenium-catalyzed Fujiwara-Moritani reaction (oxidative-Heck reaction) of Weinreb amides is reported herein. The reaction affords exclusively ortho-C-H olefination products, has excellent substrate scope and tolerates halogen functionalities, w
Autor:
Manmohan Kapur, Riki Das
Publikováno v:
Chemistry, an Asian journal. 10(7)
The ruthenium-catalyzed Fujiwara-Moritani reaction (oxidative-Heck reaction) of Weinreb amides is reported herein. The reaction affords exclusively ortho-C-H olefination products, has excellent substrate scope and tolerates halogen functionalities, w