Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Rik H. Verschueren"'
Publikováno v:
Molecules, Vol 24, Iss 11, p 2122 (2019)
This review provides an overview of synthetic transformations that have been performed by both electro- and photoredox catalysis. Both toolboxes are evaluated and compared in their ability to enable said transformations. Analogies and distinctions ar
Externí odkaz:
https://doaj.org/article/4b28e69e6bc6417b8ca525456ff2760f
Autor:
Thijs Stuyver, Rik H. Verschueren, Freija De Vleeschouwer, Ruben Van Lommel, Wim M. De Borggraeve
Publikováno v:
Organic Letters. 24:1-5
Herein, the effects of an electric field on radicals are investigated for a set of model radicals with varying complexity. An electric field impacts the intrinsic philicity of a radical, as quantified by the global electrophilicity index, ω. The ext
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cecd2e0493fe053c2f9d0c775a824cf3
https://doi.org/10.1021/acs.orglett.1c02935
https://doi.org/10.1021/acs.orglett.1c02935
Publikováno v:
Organic & Biomolecular Chemistry. 19:5782-5787
An efficient, scalable and sustainable method for the quantitative deprotection of the tert-butyl carbamate (N-Boc) protecting group is described, using down to near-stoichiometric amounts of hydrogen chloride gas in solvent-free conditions. We demon
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::20a911691709373fbcfaaf27870706ac
https://doi.org/10.1039/d1ob00728a
https://doi.org/10.1039/d1ob00728a
Autor:
Michael S. Perryman, Julian Riegger, Julie Schmauck, Bertrand Schweitzer-Chaput, Martin Breugst, Huilan Yue, Rik H. Verschueren, Martin Klussmann
Publikováno v:
Chemistry – A European Journal. 25:9088-9097
In this work, the reactivities of acetonyl and benzoyl radicals in aromatic substitution and addition reactions have been compared in an experimental and computational study. The results show that acetonyl is more electrophilic than benzoyl, which is
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1f4564ba8ceaf3d97073e23fdb940e73
https://doi.org/10.1002/chem.201901439
https://doi.org/10.1002/chem.201901439