Zobrazeno 1 - 10
of 89
pro vyhledávání: '"Richard N. Sheppard"'
Autor:
William P. Griffith, David J. Williams, Richard N. Sheppard, Andrew J. P. White, Bernardeta C. Parkin, Helena I. S. Nogueira
Publikováno v:
J. Chem. Soc., Dalton Trans.. :1775-1781
The new complexes [MO2L2]2–(H2L = 2,3- or 3,4-dihydroxybenzoic acid, 2,3-H2dhb or 3,4-H2dhb, M = Mo, W or Os; H2L = 2,6-dihydroxybenzoic acid, 2,6-H2dhb, M = Mo), [OsO2(py)2(2,6-dhb)](py = pyridine), [ReOl(PPh3)2L](H2L = 2,3-, 3,4- or 2,6-H2dhb) an
Publikováno v:
J. Chem. Soc., Perkin Trans. 1. :1121-1125
A new group of microbial metabolites, designated penitremones A–C, have been characterised by mass spectrometry and 1H and 13C NMR spectroscopy as 10-keto, 11,33-dihydro-variants of the penitrem indole-isoprenoid skeleton. The principal metabolite
Autor:
Peter G. Mantle, John N. Bilton, Karen A. Gurney, Jane M. Boyes-Korkis, Richard N. Sheppard, Julia Penn
Publikováno v:
Journal of Natural Products. 56:1707-1717
A novel bensodiasepine metabolite of an isolate of Penicillium aurantiogriseumfrom Yugoslavia has been characterised from spectral and biosynthetic evidence. The compound, anacine [1], has been produced on the 60-lirer fermenter scale after extensive
Autor:
John N. Bilton, Peter G. Mantle, Lucy J. Wigley, Richard Swift, Julia Penn, Richard N. Sheppard
Publikováno v:
Phytochemistry. 32:1431-1434
The structures of janthitrems B and C, the two most abundant tremorgenic mycotoxins produced by certain isolates of Penicillium janthinellum from New Zealand and Australia, have been elucidated by NMR spectroscopy. The compounds differ only by the ox
Publikováno v:
ChemInform. 22
The work describes a unified strategy towards the preparation of model hydroxydihydrofuran acetal fragments (2) (3) and (45) common to the potent insect antifeedant and growth disruption agent azadirachtin (1). These units, along with other analogues
Autor:
M. S. J. Simmonds, David J. Williams, Wood Anthony, E. D. Morgan, Richard N. Sheppard, Steven V. Ley, James C. Anderson, Stephen C. Smith, Alexandra M. Z. Slawin, W. M. Blaney
Publikováno v:
ChemInform. 23
Publikováno v:
ChemInform. 23
A prominent novel analogue of penitrem A has been resolved from the tremorgenic alkaloids of a strain of Penicillium nigricans and the structure, elucidated by NMR spectroscopy, shown to involve the terminal diterpenoid isoprene in a cyclisation whic
Autor:
M. Vicens, Angel Terrón, David M. L. Goodgame, Virtudes Moreno, J. J. Fiol, Richard N. Sheppard
Publikováno v:
ChemInform. 23
The synthesis in very mild conditions of three new nicotinic acid complexes of Cr(III) are reported. The D NMR study of the d2-nicotinic acid complexes reveals that nicotinic acid is bound to chromium(III) through the carboxylic group in all cases. T
Publikováno v:
ChemInform. 23
The structure of a novel indole alkaloid, glyantrypine 2, a main secondary metabolite of Aspergillus clavatus has been elucidated by biosynthetic evidence, mass spectrometry and 1H and 13C NMR techniques. The compound extends the variety of metabolit
Autor:
David J. Williams, Wood Anthony, Steven V. Ley, Richard N. Sheppard, Hartmuth C. Kolb, Stephen C. Smith, Alexandra M. Z. Slawin
Publikováno v:
ChemInform. 24
This paper describes a detailed analysis of the influence of various substituents on the stereochemical outcome of the intramolecular Diels–Alder cyclisation of a number of ether-linked trienes. In particular, the role of diene planarity in governi