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pro vyhledávání: '"Richard J. Seacome"'
Autor:
Gareth J. Rowlands, Richard J. Seacome
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 5, Iss 1, p 9 (2009)
This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chi
Externí odkaz:
https://doaj.org/article/6dbe64837206410c9889f775106f5d6d
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 39(15)
Two planar chiral heteroaryl monophosphines have been synthesised and studied. The phosphines are readily prepared from 4-imidazole[2.2]paracyclophane by selective deprotonation and reaction with the appropriate dialkylchlorophosphines. The planar ch
Autor:
Richard J. Seacome, Gareth J. Rowlands
Publikováno v:
Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry, Vol 5, Iss 1, p 9 (2009)
Beilstein Journal of Organic Chemistry, Vol 5, Iss 1, p 9 (2009)
This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chi
Publikováno v:
Organic & Biomolecular Chemistry. 3:3873
The ortho-lithiation of one diastereoisomer of 4-tert-butylsulfinyl[2.2]paracyclophane is the key step to the synthesis of a range of 4,5-disubstituted [2.2]paracyclophane derivatives.