Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Renita Thim"'
Autor:
Theresa E. Rieser, Renita Thim-Spöring, Dorothea Schädle, Peter Sirsch, Rannveig Litlabø, Karl W. Törnroos, Cäcilia Maichle-Mössmer, Reiner Anwander
Publikováno v:
Journal of the American Chemical Society. 144(9)
Group 3- and 4f-element organometallic chemistry and reactivity are decisively driven by the rare-earth-metal/lanthanide (Ln) ion size and associated electronegativity/ionicity/Lewis acidity criteria. For these reasons, the synthesis of terminal "uns
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aeee0ce46827c3275e4b1ce8693f16e3
https://pubmed.ncbi.nlm.nih.gov/35212218
https://pubmed.ncbi.nlm.nih.gov/35212218
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
A series of solvent‐free heteroleptic terminal rare‐earth‐metal alkyl complexes stabilized by a superbulky tris(pyrazolyl)borato ligand with the general formula [TptBu,MeLnMeR] have been synthesized and fully characterized. Treatment of the het
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9d5006f7b1f787cf5174da4eba6d6232
https://doi.org/10.1002/chem.201903606
https://doi.org/10.1002/chem.201903606
Publikováno v:
Organometallics. 37:2769-2777
The half-sandwich diiodide complexes [Cp*LnI2]x (Ln = Y, Lu), obtained in high yields from Cp*Ln(AlMe4)2 (Cp*= C5Me5) and 2 equiv of ISiMe3, reacted with 2 equiv of potassium benzyl KCH2Ph in THF to afford complexes Cp*Ln(CH2Ph)2(thf). Protonolysis o
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b214e3621ef370ca97c2ad0e925a87c5
https://doi.org/10.1021/acs.organomet.8b00420
https://doi.org/10.1021/acs.organomet.8b00420
Publikováno v:
Organometallics. 37:2563-2570
The four-membered metallacyclic lutetium complexes TptBu,MeLu[CH2(SiMe2)NR] were synthesized via protonolysis of TptBu,MeLuMe2 (TptBu,Me = hydrotris(3-methyl-5-tert-butylpyrazolyl)borato) with silylamines HN(SiMe3)R (R = SiMe3, C6H3(CF3)2-3,5 (ArCF3)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7d8d2e37a63870caad91bee0095d51bf
https://doi.org/10.1021/acs.organomet.8b00312
https://doi.org/10.1021/acs.organomet.8b00312
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 25(2)
Protonolysis of lanthanide tris(tetramethylaluminate)s with two equivalents of 2,6-diisopropylaniline affords LaIII and CeIII diimide compounds Ln[(μ-NC6 H3 iPr2 -2,6)2 AlMe2 ](thf)4 featuring a bidentate AlMe2 -linked diimido ligand. As revealed fo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::15931d5ce437ce47800ee03d59be16d6
https://pubmed.ncbi.nlm.nih.gov/30352133
https://pubmed.ncbi.nlm.nih.gov/30352133