Zobrazeno 1 - 10
of 94
pro vyhledávání: '"Rene J. Lachicotte"'
Autor:
William D. Jones, Matthew R. Grochowski, Stephen S. Oster, William W. Brennessel, Rene J. Lachicotte
Publikováno v:
Organometallics. 29:4923-4931
The rhodium dimer [Rh(dippe)(μ-H)]2 (1) reacts with dibenzothiophene to form the C−S cleavage product [Rh2(dippe)2(μ-SC12H9)(μ-H)] (3). Complex 1 also reacts with 4-methyldibenzothiophene and 4,6-dimethyldibenzothiophene to form [Rh2(dippe)2(μ-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cfcf29652ad1f20b77ce9d54abbd060a
https://doi.org/10.1021/om1001815
https://doi.org/10.1021/om1001815
Autor:
Lucio Randaccio, Patricia A. Marzilli, Patrizia Siega, Rene J. Lachicotte, Luigi G. Marzilli, Scott J. Moore
Publikováno v:
Inorganica Chimica Acta. 362:993-1002
We prepared two new analogues of ([CH 3 CO((DO)(DOH)pn)L] + ) [(DO)(DOH)pn = N 2 ,N 2 '-propane-1,3-diylbis(2,3-butanedione-2-imine-3-oxime)] B 12 models but with an O-BF 2 -O unit replacing the O-H···O unit as follows: [CH 3 Co((DO)(DOBF 2 )pn)L]
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::642ba689608be17a91b8cf3018bf4b8b
https://doi.org/10.1016/j.ica.2007.09.004
https://doi.org/10.1016/j.ica.2007.09.004
Publikováno v:
Organometallics, 28(22), 6524-6530. American Chemical Society
Carbon-carbon bond activation reactions of asymmetric acetylene derivatives of the type L2Pt(PhC=CR) were studied with 1,2-bis(diisopropylphosphino)ethane (dippe), 1,2-bis(di-tert-butylphosphino)ethane (dtbpe), and 1-diisopropylphosphino-2-dimethylam
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f7f04358ab4cbefb329396d3dbc7da9e
https://doi.org/10.1021/om900413a
https://doi.org/10.1021/om900413a
Autor:
Rene J. Lachicotte, Jeremy M. Smith, Santiago Alvarez, Javier Vela, Patrick L. Holland, Christine Flaschenriem, Jordi Cirera
Publikováno v:
Inorganic Chemistry. 46:60-71
Six of the seven iron atoms in the iron-molybdenum cofactor of nitrogenase display an unusual geometry, which is distorted from the tetrahedral geometry that is most common in iron-sulfur clusters. This distortion pulls the iron along one C3 axis of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a491d1d935a3ca912ca3a31b3c114c64
https://doi.org/10.1021/ic0609148
https://doi.org/10.1021/ic0609148
Autor:
Savariraj Kingsley, Rene J. Lachicotte, Thomas R. Cundari, Javier Vela, Patrick L. Holland, Christine Flaschenriem, Sridhar Vaddadi
Publikováno v:
Angewandte Chemie. 118:1637-1641
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::22e68512a7817ae30885b56c4523959f
https://doi.org/10.1002/ange.200503535
https://doi.org/10.1002/ange.200503535
Autor:
Azwana R. Sadique, Patrick L. Holland, Javier Vela, Jeremy M. Smith, Rene J. Lachicotte, Thomas R. Cundari, Gudrun Lukat-Rodgers, Christine Flaschenriem, Kenton R. Rodgers
Publikováno v:
Journal of the American Chemical Society. 128:756-769
Understanding the interaction of N2 with iron is relevant to the iron catalyst used in the Haber process and to possible roles of the FeMoco active site of nitrogenase. The work reported here uses synthetic compounds to evaluate the extent of NN weak
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fe9aedcc51a0542bd73044c93d9632c5
https://doi.org/10.1021/ja052707x
https://doi.org/10.1021/ja052707x
Autor:
Christine Flaschenriem, Jeremy M. Smith, Nicole A. Ketterer, Javier Vela, Rene J. Lachicotte, Ying Yu, Patrick L. Holland
Publikováno v:
Journal of the American Chemical Society. 127:7857-7870
Transition metal fluoride complexes are of interest because they are potentially useful in a multitude of catalytic applications, including C-F bond activation and fluorocarbon functionalization. We report the first crystallographically characterized
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::11aaf4100f56d2e84a869f68a4361dbd
https://doi.org/10.1021/ja042672l
https://doi.org/10.1021/ja042672l
Autor:
Rene J. Lachicotte, Patrick L. Holland, Elizabeth A. Gregory, Sridhar Vaddadi, Javier Vela, Thomas R. Cundari, and Christine J. Flaschenriem, Jeremy M. Smith
Publikováno v:
Organometallics. 23:5226-5239
High-spin organometallic complexes have not received extensive mechanistic study, despite their potential importance as unsaturated intermediates in catalytic transformations. We have found that, with a suitably bulky bidentate ligand, three-coordina
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a62da41c1a4ad5dc49e604f119761084
https://doi.org/10.1021/om049415+
https://doi.org/10.1021/om049415+
Publikováno v:
Inorganic Chemistry. 42:1720-1725
Nickel(II) chloride forms a complex with tetrahydrofuran, NiCl(2)(THF)(1.5), that can be used to prepare nickel chloride complexes of a bulky beta-diketiminate ligand L(Me). [L(Me)NiCl](2) and L(Me)NiCl(2)LiTHF(2), which have tetrahedral geometries i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::04120525f27d864d2b7b1848891cf97a
https://doi.org/10.1021/ic025986n
https://doi.org/10.1021/ic025986n
Publikováno v:
Organometallics. 21:5320-5333
The reductive elimination of neopentane from (dtbpm)Pt(Np)H (dtbpm = bis(di-tert-butylphosphino)methane, Np = neopentyl) results in the formation of the highly reactive intermediate [(dtbpm)Pt0]. This species reacts with a variety of electron-deficie
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::683075e2c6b77224901544d3c16dc36c
https://doi.org/10.1021/om020459x
https://doi.org/10.1021/om020459x