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Autor:
Diego Sorbelli, Elisa Rossi, Remco W.A. Havenith, Johannes E.M.N. Klein, Leonardo Belpassi, Paola Belanzoni
Publikováno v:
INORGANIC CHEMISTRY
Inorganic Chemistry, 61(19). AMER CHEMICAL SOC
Inorganic Chemistry, 61(19). AMER CHEMICAL SOC
The unconventional carbon dioxide insertion reaction of a gold-aluminyl [tBu3PAuAl(NON)] complex has been recently shown to be related to the electron-sharing character of the Au-Al bond that acts as a nucleophile and stabilizes the insertion product