Zobrazeno 1 - 10
of 126
pro vyhledávání: '"Reinhard Stößer"'
Autor:
Werner Herrmann, Reinhard Stößer
Publikováno v:
Molecules, Vol 18, Iss 6, Pp 6679-6722 (2013)
In order to present the relationship between ESR spectroscopy and isotope effects three levels are considered: (i) ESR spectroscopy is described on a general level up to the models for interpretation of the experimental spectra, which go beyond the u
Externí odkaz:
https://doaj.org/article/2fbb9452b515422f8b593be786c724e5
Publikováno v:
European Journal of Inorganic Chemistry. 2015:4227-4236
Hydrogen atoms were generated in the matrices AlF3 and CaF2 at room temperature by ionizing radiation (γ and UV) and were investigated by electron paramagnetic resonance spectroscopy. To gain information on the nature of the hydrogen precursors and
Publikováno v:
Angewandte Chemie International Edition. 54:11791-11794
The first coupled operando EPR/UV-Vis/ATR-IR spectroscopy setup for mechanistic studies of gas-liquid phase reactions is presented and exemplarily applied to the well-known copper/TEMPO-catalyzed (TEMPO=(2,2,6,6-tetramethylpiperidin-1-yl)oxyl) oxidat
Autor:
Haijun Jiao, Anton Dimitrov, Angelika Brückner, Wolfgang Baumann, Jabor Rabeah, Jörg Radnik, Annette-Enrica Surkus, Reinhard Stößer, Ursula Bentrup
Publikováno v:
Organometallics. 33:4905-4910
In this work, the new organic–inorganic hybrid compound Ph4P[(V2O3)2(PhAsO3)4⊂F] (VAsF) has been prepared and characterized by single-crystal XRD and multinuclear magnetic resonance (1H, 19F, 31P, and 51V). Redox properties and thermal stability
Autor:
Reinhard Stößer, Michael Menzel, C. Willgeroth, Franziska Emmerling, Michael Feist, H. Reuther
Publikováno v:
Journal of Solid State Chemistry. 202:173-190
The Goldschmidt reaction (2Al+α-Fe{sub 2}O{sub 3}) was investigated both under mechanical and thermal activation by employing a combination of analytical methods such as ESR and Mossbauer spectroscopy, magnetic susceptibility, X-ray powder diffracti
Publikováno v:
Advanced Synthesis & Catalysis. 354:2648-2652
A new concept to access unsymmetrical 1,2-diols with high yields is reported. This new methodology is based on a retropinacol/cross-pinacol coupling process. This transformation is characterized by its operational simplicity and very mild reaction co
Publikováno v:
The Journal of Physical Chemistry A. 116:952-961
By means of continuous wave electron spin resonance (cw ESR) in the X and L bands, the spin exchange of series of different concentrations of the spin probes 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO), 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl
Autor:
Reinhard Stößer, Michael W. Linscheid, Hans-Hubert Borchert, Werner Herrmann, Ulrike Hochkirch
Publikováno v:
Analytical and Bioanalytical Chemistry. 401:901-907
Electron spin resonance spectroscopy and mass spectrometry are two analytical methods that are very rarely used in combination. In this paper, we will show that the methods complement one another in the example of the distribution of stable nitroxide
Publikováno v:
The Journal of Physical Chemistry A. 115:2939-2952
Comprehensive examinations of the motional properties (rotational correlation time τ(R)) and the spin exchange ω(SS) of the spin probe TEMPOL have been carried out using ESR spectroscopy in two different solvents. For the first time, the dynamic pa
Autor:
Christina Knispel, Reinhard Stösser, Christian Limberg, Stefan Pfirrmann, Christian Herwig, Eckhard Bill, Beatrice Braun
Publikováno v:
Journal of the American Chemical Society. 132:13684-13691
An investigation concerning the stepwise reduction of the β-diketiminato nickel(II) hydride dimer [LNi(μ-H)(2)NiL], 1 (L = [HC(CMeNC(6)H(3)(iPr)(2))(2)](-)), has been carried out. While the reaction with one equivalent of potassium graphite, KC(8),