Zobrazeno 1 - 10
of 57
pro vyhledávání: '"Rein U. Kirss"'
Autor:
Benjamin S. Rich, Noah B. Bissonnette, Alejandra Duran Balsa, Mulan Yang, Hope Meikle, Nithin Chintala, Sijia S. Dong, Rein U. Kirss
Publikováno v:
New Journal of Chemistry. 46:6603-6608
Kinetic measurements of the reaction between CpRu(PPh3)2Cl (1a) and 1-bromobutane reveal a nearly first order dependence on the concentration of haloalkane and a negative entropy of activation, ΔS† < 0.
Autor:
Noah B. Bissonnette, Mulan Yang, Thomas Pioch, Willem Bussink, Connor Gaillin, Eric McCarthy, Linh Dang, Rein U. Kirss
Publikováno v:
Polyhedron. 217:115719
Autor:
Miles Clark, Bakar Hassan, Rein U. Kirss, Connor Delaney, Mathew Eaton, Olivia Hendricks, David E. Hill, Duy Khoi Dang
Publikováno v:
RSC Advances. 7:34425-34434
The kinetics of phosphine substitution in CpRu(PPh3)2X (X = Br, 1b, X = I, 1c, X = N3, 1d, and X = NCO, 1e) have been measured under pseudo-first order conditions in THF solution and compared with data for CpRu(PPh3)2X (1a). The relative rate of subs
Autor:
Rebecca R. Conry, Olivia Hendricks, Michael J. Verschoor-Kirss, Rein U. Kirss, Carla M. Verschoor
Publikováno v:
Inorganica Chimica Acta. 450:30-38
The electrochemistry of ferrocene-substituted phosphines suggests electron loss from a largely ferrocene-based HOMO with significant phosphorus character rather than the exclusive oxidation of iron. In contrast, studies of the chemical oxidation of f
Publikováno v:
Dalton Trans.. 43:15221-15227
The kinetics of phosphine substitution in CpRu(PAr3)2Cl by PMePh2 under pseudo-first order conditions in CDCl3 have been measured for PAr3 = PPh3, 1a, PPh2(p-tol), 1b, P(p-tol)3, 1c, P(p-CH3OC6H4)3, 1d, and P(p-FC6H4)3), 1e. Activation parameters cha
Autor:
Catherine Cote, Rein U. Kirss
Publikováno v:
Inorganica Chimica Acta. 363:2520-2525
Copper(I) catalyzed [3+2] cycloaddition reactions between 5-ethynylbipyridine and benzyl, p -methylbenzyl, or m -bromobenzyl azides yields the corresponding 1-benzyl-4-(5-bipyridyl)-1H-1,2,3-triazoles 1 – 3 . Reaction between 1 – 3 and [NEt 4 ] 2
Autor:
Rein U. Kirss, Christoph Frommen, Joszef Kreisz, William M. Reiff, William Feighery, Michael Verschoor-Kirss
Publikováno v:
Journal of Organometallic Chemistry. 694:3262-3269
Copper catalyzed [3+2] cycloaddition reactions between ethynylferrocene and benzylazides yields 1-benzyl-4-ferrocenyl-1,2,3-triazoles ( 2 – 5 ). Reaction between phenylacetylene and azidoferrocene yields 1-ferrocenyl-4-phenyl-1,2,3-triazole ( 6 ).
Autor:
Rein U. Kirss, Matthew Daniels
Publikováno v:
Journal of Organometallic Chemistry. 692:1716-1725
Exchange of PMe 2 Ph for PPh 3 in (η 5 -pentadienyl)ruthenium{bis(triphenylphosphine)}chloride, (η 5 -C 5 H 7 )Ru(PPh 3 ) 2 Cl ( 1 ) under first order conditions proceeds rapidly in THF at room temperature. A pseudo-first order rate constant of 17
Publikováno v:
Inorganica Chimica Acta. 359:4393-4397
Five bis(3-aryl-6,6-dimethylcyclohexadienyl)ruthenium complexes (4a–4e) are prepared by reactions between di-l-chlorodichlorobis[(1–3g:6–8g)-2,7-dimethyl-octadienyl]diruthenium and the corresponding dienes. The larger aryl substituents increase
Publikováno v:
Organometallics. 24:48-52
The anodic electrochemistry of several compounds containing two or three ferrocenyl moieties linked by a phosphine or phosphine chalcogenide group has been studied in dichloromethane containing [NBu4][TFAB], where TFAB is the tetrakis(perfluoroaryl)b