Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Reimund Jotter"'
Autor:
Hans-Jürgen Fachmann, Reimund Jotter, Alfons Kubny, Joachim Wagner, Norbert Baumann, Gerhard Czack, Brigitte Heibel, Peter Merlet
The present volume is the first of a series describing acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The acyclic sw-N compounds are arranged according to the coordination number of the sulfur. Neutral compounds are described b
Publikováno v:
S Sulfur-Nitrogen Compounds ISBN: 9783662063538
Sulfur-Nitrogen Compounds ISBN: 9783662063569
Sulfur-Nitrogen Compounds ISBN: 9783662063569
Flash vacuum pyrolysis of 5-phenyl-1,2,3,4-thiatriazole produces SNN and C6H5CN. It was carried out at temperatures between 300 and 400 °C/10−3 to 10−5 Torr in an apparatus enabling contact times of ca. 1 ms. SNN can be isolated as a solid (toge
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::34a16f42bd3a47a2942a355c668978e8
https://doi.org/10.1007/978-3-662-06351-4_5
https://doi.org/10.1007/978-3-662-06351-4_5
Publikováno v:
S Sulfur-Nitrogen Compounds ISBN: 9783662063538
Sulfur-Nitrogen Compounds ISBN: 9783662063569
Sulfur-Nitrogen Compounds ISBN: 9783662063569
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4af82b5f62df6d68b681dc99ea92876c
https://doi.org/10.1007/978-3-662-06351-4_9
https://doi.org/10.1007/978-3-662-06351-4_9
Publikováno v:
S Sulfur-Nitrogen Compounds ISBN: 9783662063538
Sulfur-Nitrogen Compounds ISBN: 9783662063569
Sulfur-Nitrogen Compounds ISBN: 9783662063569
The SNS species, a radical, was detected IR spectroscopically only in an Ar matrix. No other unambiguous spectroscopic identification has yet been reported.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3aca7746ca01a35fef03a24298046c50
https://doi.org/10.1007/978-3-662-06351-4_2
https://doi.org/10.1007/978-3-662-06351-4_2
Publikováno v:
Sulfur-Nitrogen Compounds ISBN: 9783662063569
S Sulfur-Nitrogen Compounds ISBN: 9783662063538
S Sulfur-Nitrogen Compounds ISBN: 9783662063538
S=NH, the parent compound of the sulfur imide compounds, has not yet been isolated in the free state. However, it was possible to stabilize the molecule by coordination as a six-electron ligand to two Fe atoms like in Fe2(CO)6(μ-S=NH) [1]; see p. 2.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b0d72ae943cb0369f3ffa978be798e53
https://doi.org/10.1007/978-3-662-06354-5_1
https://doi.org/10.1007/978-3-662-06354-5_1
Publikováno v:
Sulfur-Nitrogen Compounds ISBN: 9783662063569
S Sulfur-Nitrogen Compounds ISBN: 9783662063538
S Sulfur-Nitrogen Compounds ISBN: 9783662063538
The title compound was prepared by reacting S4N4 with sulfur and ASF, in SO2 in the presence of a trace amount of bromine via 1/2 S8 + S4N4 + 6 ASF5→4 S2N+ AsF 6 - + 2 AsF3. This is the only route which gives high yields of a crystalline, soluble S
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a6bb2059e784ea37264e27bd0ed2473b
https://doi.org/10.1007/978-3-662-06354-5_4
https://doi.org/10.1007/978-3-662-06354-5_4
Publikováno v:
S Sulfur-Nitrogen Compounds ISBN: 9783662063538
Sulfur-Nitrogen Compounds ISBN: 9783662063569
Sulfur-Nitrogen Compounds ISBN: 9783662063569
Despite the fact that oximes are one of the best known carbonyl derivatives, only a few sulfur-analog thiooximes are known because of their instability. The existence of thiooximate ions could be established by certain reactions: for example, CH2=NS
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ae36b4430902dc25402e2884b4e3e9b3
https://doi.org/10.1007/978-3-662-06351-4_8
https://doi.org/10.1007/978-3-662-06351-4_8