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pro vyhledávání: '"Reikichi Iwamoto"'
Autor:
Reikichi Iwamoto
Publikováno v:
Bulletin of the Chemical Society of Japan. 92:1117-1126
In the present paper we have studied interactions of the N and NH of alkylamines with water. We analyzed the property from the infrared and near-infrared absorptions that hydration causes to tribut...
Autor:
Reikichi Iwamoto, Rika Harui
Publikováno v:
Bulletin of the Chemical Society of Japan. 91:1267-1274
The aim of the present study is to investigate how F substitution influences the hydrogen-bonding of the CH to water of an alkane. For this purpose we have comparatively studied the hydrogen bondin...
Publikováno v:
Bulletin of the Chemical Society of Japan. 90:527-536
We study the hydrogen-bonding structure of the water in polycarbonate (PC) (OC6H4C(CH3)2C6H4OCO)n by near- and mid-infrared spectroscopy. We extensively analyze the effects of the hydration interac...
Autor:
Hiroshi Kusanagi, Reikichi Iwamoto
Publikováno v:
The Journal of Physical Chemistry A. 119:2885-2894
We have studied the state of the water contained in poly(ethylene terephthalate) (PET), which consists of repeat units of OCC6H4COOCH2CH2O, in variously hydrated states. We first determined the hydration structure of the water therein not only from i
Autor:
Reikichi Iwamoto
Publikováno v:
The Journal of Physical Chemistry A. 114:7398-7407
Hydration property of amide C=O was investigated from the OH stretching fundamentals and the first combinations of the water in the hydrate, formed in hydrophobic solution of an N,N-dialkyl amide ((CH(3)CH(2))(2)NCO(CH(2))(10)CH(3)) in heptane. The p
Autor:
Masahiro Sato, Reikichi Iwamoto
Publikováno v:
The Journal of Physical Chemistry A. 113:13998-14007
In the present paper we characterize the hydration shell around a Li ion, as -SO(3)(-)Li(+), from a series of infrared spectra of the hydrated Li salt in a sample of Nafion. The infrared spectrum significantly changes through prolonged dehydration un
Autor:
Reikichi Iwamoto, Hiroshi Kusanagi
Publikováno v:
The Journal of Physical Chemistry A. 113:5310-5316
This paper reports the structure of the hydrate complex of an isolated alcoholic OH, produced in a small amount in hydrophobic solution in heptane. The structure was determined from the changes, caused by hydration, in the infrared and near-infrared
Autor:
Reikichi Iwamoto
Publikováno v:
Applied Spectroscopy. 63:354-362
In the present paper we report that near-infrared spectroscopy is a useful tool for analyzing solutes in solution in common organic solvents. This is because the near-infrared absorptions of the solvent are not so strong as to disturb the separation
Autor:
Toshihiko Matsuda, Reikichi Iwamoto
Publikováno v:
Analytical Chemistry. 79:3455-3461
First, we developed quantitative analytical methods of water in poly(methyl methacrylate) (PMMA) in various hydrated states by utilizing the first combination and OH stretching bands of water at about 5240 and 3630 cm-1, respectively. Next, we invest
Publikováno v:
Journal of Polymer Science Part B: Polymer Physics. 44:2425-2437
We studied interactions of water with OH groups in poly(ethylene-co-vinyl alcohol) (EVOH) of the ethylene (Et) compositions of 33, 49, 75, and 89% (mol) using near-infrared spectroscopy. OH groups are mostly self-associated and only partly isolated i