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pro vyhledávání: '"Rebecca Grünbauer"'
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 647:850-856
A novel reactivity of [{Cp*Cr(CO) 3 } 2 (µ,η 1:1 ‐P 4 )] (Cp* = C 5 Me 5 ; 1 ) is reported, which utilizes the selective cleavage of the two P–Cr bonds and subsequently initiates a substituent exchange yielding P 4 butterfly compounds. By means
Publikováno v:
Chemical Communications. 57:3383-3386
The reactivity of the P4 butterfly complexes [{Cp′′′Fe(CO)2}2(μ,η1:1-P4)] (A, Cp′′′ = C5H2tBu3) and [{Cp*Cr(CO)3}2(μ,η1:1-P4)] (B, Cp* = C5(CH3)5) towards the N-heterocyclic carbene IMe (1,3,4,5-tetramethyl-imidazol-2-ylidene) is repo
Publikováno v:
Chemical communications (Cambridge, England). 57(27)
The reactivity of the P
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
The versatile coordination behavior of the P4 butterfly complex [{Cp*Cr(CO)3}2(μ,η1:1‐P4)] (1) towards Lewis acidic pentacarbonyl compounds of Cr, Mo and W is reported. The reaction of 1 with [W(CO)4(nbd)] (nbd=norbornadiene) yields the complex [
Autor:
Rebecca Grünbauer, Micah S. Ziegler, David W. Small, Amélie Nicolay, Manfred Scheer, T. Don Tilley
Publikováno v:
Chemical Science
A dicopper complex featuring a symmetrically bridging nitrile ligand and supported by a binucleating naphthyridine-based ligand was treated with phosphaalkynes to yield dicopper complexes that exhibit phosphaalkynes in rare μ-η2:η2 binding modes.<
Publikováno v:
Inorganica Chimica Acta. 518:120234
The reaction of the P4 butterfly compound [{Cp'''Fe(CO)2}2(μ,η1:1-P4)] (1, Cp''' = C5H2tBu3) towards various transition metal complexes is investigated. On the one hand, the reaction of 1 with [(PPh3)Au(tht)][PF6] (tht = tetrahydrothiophene) and [M