Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Reactive precursors"'
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
Nature Communications
Nature Communications
Site-selective modification of oligonucleotides serves as an indispensable tool in many fields of research including research of fundamental biological processes, biotechnology, and nanotechnology. Here we report chemo- and regioselective modificatio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2bcbfd8d0624a88d271716d9a6d16691
https://doaj.org/article/a87f440e559c43fb9ceb54897722cfc7
https://doaj.org/article/a87f440e559c43fb9ceb54897722cfc7
Autor:
Bas de Bruin, Max C. Holthausen, Christian Würtele, Joris van Slageren, David Hunger, Sven Schneider, Jian Sun, Hendrik Verplancke, Josh Abbenseth, Martin Diefenbach
Publikováno v:
Nature Chemistry
Nature Chemistry, 12(11), 1054-1059. Nature Publishing Group
Nature Chemistry, 12(11), 1054-1059. Nature Publishing Group
Metallonitrenes (M–N) are complexes with a subvalent atomic nitrogen ligand that have been proposed as key reactive intermediates in nitrogen atom transfer reactions. However, in contrast to the common classes of nitride complexes (M≡N) and organ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::171c50fc84d3e6ef6af43eb394ac5a01
https://doi.org/10.1038/s41557-020-0522-4
https://doi.org/10.1038/s41557-020-0522-4
Publikováno v:
Nature Communications
Nature Communications, 2022, 13 (1), pp.223. ⟨10.1038/s41467-021-27809-0⟩
Nature Communications, Vol 13, Iss 1, Pp 1-7 (2022)
Nature Communications, 2022, 13 (1), pp.223. ⟨10.1038/s41467-021-27809-0⟩
Nature Communications, Vol 13, Iss 1, Pp 1-7 (2022)
During the last years we have witnessed progressive evolution of preparation of acenes with length up to dodecacene by on-surface synthesis in ultra-high vacuum or generation of acenes up to decacene in solid matrices at low temperatures. While these
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19278c77e41cd767df174ea4a0c04c25
https://doi.org/10.1038/s41467-021-27809-0
https://doi.org/10.1038/s41467-021-27809-0
Autor:
Yao Fu, Min Zheng, Yinuo Yang, Xiaoguo Zhou, Feng-Lian Zhang, Shi-Chao Ren, Ai-Qing Xu, Yi-Feng Wang
Publikováno v:
Nature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
Nature Communications
Nature Communications
Organoboron compounds are highly valuable in synthetic chemistry. In particular, α-borylcarbonyl compounds have shown versatile synthetic applications, owing to fruitful chemistries of both the boryl and carbonyl moieties. However, the synthesis of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8bc74d7ff788a439214ee3c0753981ee
https://doaj.org/article/dc9d93b0df7d48e9b233f69886c8cf94
https://doaj.org/article/dc9d93b0df7d48e9b233f69886c8cf94
Autor:
Shengzu Duan, Patrick J. Walsh, Guogang Deng, Hongbin Zhang, Xiao-Dong Yang, Zhuo Chen, Jing Wang, Tongqi Liu, Wen Chen
Publikováno v:
Nature Communications
Nature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
Nature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
Allylation of nucleophiles with highly reactive electrophiles like allyl halides can be conducted without metal catalysts. Less reactive electrophiles, such as allyl esters and carbonates, usually require a transition metal catalyst to facilitate the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::55dbcce6d19cf0dd26c62568c0c19104
https://doi.org/10.1038/s41467-021-24027-6
https://doi.org/10.1038/s41467-021-24027-6
Autor:
Ganesamoorthy, Chelladurai, Helling, Christoph, Wölper, Christoph, Frank, Walter, Bill, Eckhard, Cutsail, George E., Schulz, Stephan
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
Nature Communications
Nature Communications
Neutral stibinyl and bismuthinyl radicals are typically short-lived, reactive species. Here we show the synthesis and solid-state structures of two stable stibinyl [L(Cl)Ga]2Sb· 1 and bismuthinyl radicals [L(I)Ga]2Bi· 4, which are stabilized by ele
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid_dedup__::f29fa34621deb19bb1593b40c6c4311e
http://link.springer.com/article/10.1038/s41467-017-02581-2
http://link.springer.com/article/10.1038/s41467-017-02581-2
Publikováno v:
Scientific Reports
Scientific Reports, Vol 9, Iss 1, Pp 1-9 (2019)
Scientific Reports, Vol 9, Iss 1, Pp 1-9 (2019)
The highly selective synthesis of spirobiindanes, alkenyl chlorides, and monofluoroalkenes via the cleavage of inert C(sp3)–F bonds in unactivated gem-difluoroalkanes using readily available and inexpensive aluminum-based Lewis acids of low toxicit
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d9c8256ea41fdef4eb2db804096761d3
https://doi.org/10.1038/s41598-019-55206-7
https://doi.org/10.1038/s41598-019-55206-7
Publikováno v:
Nature Communications
Nature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
Nature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
As a versatile intermediate, difluorocarbene is an electron-deficient transient species, meaning that its oxidation would be challenging. Herein we show that the oxidation of difluorocarbene could occur smoothly to generate carbonyl fluoride. The oxi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a95d6b1fca6ca5477fb363345ed10126
https://doi.org/10.1038/s41467-019-13359-z
https://doi.org/10.1038/s41467-019-13359-z
Akademický článek
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Kniha
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