Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Raymond Le Goaller"'
Autor:
Raymond Le Goaller, Jean-Louis Pierre
Publikováno v:
Canadian Journal of Chemistry. 55:757-765
Two methods are described for the preparation of substituted cyclopropanediols: reduction of β-diketones, and bridging of 1,2-bissiloxyalkenes; a number of the latter compounds were prepared by a new method. [Journal translation]
Publikováno v:
Journal of the American Chemical Society. 106:1694-1698
Publikováno v:
Canadian Journal of Chemistry. 67:104-108
Iodine nitrate or bromine nitrate in acetonitrile or in chloroform react with a variety of phenolic substrates to form both halogenated and nitrated products. In the presence of strong complexing agents of halonium ions, no reaction occurs, while in
Autor:
Jean-Louis Pierre, Raymond Le Goaller
Publikováno v:
Canadian Journal of Chemistry. 56:481-486
The chemical behaviour of 1,2-bis(trimethylsiloxy)cyclopropanes is described. Acid and base solvolyses as well as reactions with chlorine and bromine occur with opening of the ring leading to α-ketols, enones and β-diketones. Ketols and enones aris
Publikováno v:
Electrochimica Acta. 27:257-261
In presence of cryptands ([2.2.2], [2.2.1] and [2.1.1]) halogens X2(bromide and iodine) give rise to the formation of an halonium ion complex in chloroformic solution. Preliminary voltammetric studies of halide and halogen alone allow to measure the
Publikováno v:
Canadian Journal of Chemistry. 60:1933-1941
Ethoxy-alkenes act as excellent carbene acceptors in the methylmonohalogenocyclopropanation reaction mediated by 1,1-dichloroethane and iodide-ion free methyl iodide. As well as chlorinated adducts, a large proportion of brominated products are obtai
Publikováno v:
Tetrahedron Letters. 25:2223-2226
The diprotonated cryptand ∣2.2.2 H 2 ∣ 2+ is formed by the addition in nitromethane 1 of two equivalent of trifluoroacetic acid (or hydroiodic acid) to the cryptate ∣2.2.2 I∣ + , I − ; the reaction is accompanied by the release of molecular
Publikováno v:
Journal de Chimie Physique. 78:421-425
L'etude du systeme l2— Et3 N dans le chloroforme est effectuee par resonance magnetique nucleaire, conductimetrie, spectroscopie dans l'ultra-violet et voltamperometrie. Les donnees experimentales mettent en evidence un complexe ionique de stœchio
Publikováno v:
Canadian Journal of Chemistry. 59:621-628
Weakly nucleophilic acceptors such as enol ethers can facilitate cycloaddition reactions with monohalocarbenoids. The high yields and stereoselection towards the more highly hindered adducts are interpreted by complexation of the oxygen atom of the s
Publikováno v:
Organic Magnetic Resonance. 1:337-340
La configuration meso ou threo de molecules diastereoisomeres est determinee a partir des spectres RMN respectifs xde chaque isomere. Les relations de symetrie (Raban et Mislow), qui existent entre protons ou groupes de ces molecules sont differentes