Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Ravichandran Khazeber"'
Publikováno v:
Nature Communications, Vol 15, Iss 1, Pp 1-8 (2024)
Abstract Circumventing the issues of conventional stereocomplexation of preformed polymers, herein, we synthesize two enantiopure polymers of opposite chirality simultaneously and in situ as their 1:1 stereocomplex via topochemical polymerization. We
Externí odkaz:
https://doaj.org/article/1049406c9aa948c4956e6a52c385e9b0
Autor:
Vignesh Athiyarath, Liby Ann Mathew, Yakai Zhao, Ravichandran Khazeber, Upadrasta Ramamurty, Kana M. Sureshan
Publikováno v:
Chemical Science. 14:5132-5140
We demonstrate the scope of combining polymorphism and topochemistry for the designed synthesis of polymorphs of a polymer. Polymorphs of a designed monomer underwent topochemical polymerization to polymer–polymorphs.
Publikováno v:
Proceedings of the National Academy of Sciences. 119
Polymers possessing helical conformation in the solid state are in high demand. We report a helical peptide-polymer via the topochemical ene-azide cycloaddition (TEAC) polymerization. The molecules of the designed Gly-Phe–based dipeptide, decorated
Publikováno v:
Angewandte Chemie (International ed. in English). 60(47)
Topochemical reactions, high-yielding solid-state reactions arising from the proximal alignment of reacting partners in the crystal lattice, do not require solvents, catalysts, and additives, are of high demand in the context of green processes and e
Publikováno v:
Angewandte Chemie International Edition. 60:25163-25163
Publikováno v:
Angewandte Chemie. 133:25367-25367