Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Ratan Logdi"'
Publikováno v:
Chemical Science. 14:5079-5086
This work reports the first catalytic N-methylation of primary amides using CO2. BICAAC plays a dual role in activating the amide and CO2 during catalysis.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::98a89564cd9064d41050b53f594d7e87
https://doi.org/10.1039/d3sc01216f
https://doi.org/10.1039/d3sc01216f
Publikováno v:
The Journal of Physical Chemistry A. 126:221-229
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d6cd55016ba4c86421c335d364b82ab0
https://doi.org/10.1021/acs.jpca.1c07918
https://doi.org/10.1021/acs.jpca.1c07918
The optical absorbance behavior of a molecule during the reaction is yet to be explored due to the deficiency in appropriate theoretical and experimental tools. In the present study, the Intrinsic Reaction Coordinate (IRC) trapping methodology is imp
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2973bbe996522cab1cd3a1dc6fcc7a0b
https://doi.org/10.26434/chemrxiv-2022-cr98c-v2
https://doi.org/10.26434/chemrxiv-2022-cr98c-v2
Activation of N_2 at an ambient condition and reduction to produce ammonia employing metal-free catalyst is one of the grand scientific problems to date. An effective appetite of carbenes towards molecular nitrogen proclaims their candidature as N_2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::46aa784ab0dc857b659d1e7be111b50f
https://doi.org/10.26434/chemrxiv-2022-cr98c
https://doi.org/10.26434/chemrxiv-2022-cr98c
Bicyclic (alkyl)(amino)carbene (BICAAC) as a metal-free catalyst for reduction of nitriles to amines
Autor:
Nimisha Gautam, Ratan Logdi, null Sreejyothi P., N. M. Rajendran, Ashwani K. Tiwari, Swadhin K. Mandal
Publikováno v:
Chemical communications (Cambridge, England). 58(18)
Bicyclic (alkyl)(amino)carbene (BICAAC) is introduced as a metal-free catalyst for the reduction of various nitriles to the corresponding amine hydrochloride salts in the presence of pinacolborane. Mechanistic investigations combining experiments and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::125d68c6439943eea777f846f8541ea8
https://pubmed.ncbi.nlm.nih.gov/35156960
https://pubmed.ncbi.nlm.nih.gov/35156960
Publikováno v:
The journal of physical chemistry. A. 126(2)
The sequestering and complete conversion of SO
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::26974e7bc6b417ea3f26e4d4d21c15ef
https://pubmed.ncbi.nlm.nih.gov/34995460
https://pubmed.ncbi.nlm.nih.gov/34995460
Publikováno v:
The journal of physical chemistry. A. 125(26)
Recent DFT based molecular engineering to obtain stable oxathiirane
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::6169ced8826692fb231e381557929d87
https://pubmed.ncbi.nlm.nih.gov/34170129
https://pubmed.ncbi.nlm.nih.gov/34170129
Publikováno v:
Journal of molecular graphicsmodelling. 93
Carbene compounds are very reactive to SO
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::af8c9c5514d7db061ed470d043e82a3f
https://pubmed.ncbi.nlm.nih.gov/31472417
https://pubmed.ncbi.nlm.nih.gov/31472417
Publikováno v:
Journal of Molecular Graphics and Modelling. 93:107437
Carbene compounds are very reactive to SO2 which assert their candidature to seize this greenhouse gas. Unfortunately, most of the carbenes which produce S,S-dioxide with SO2, undergo dissociation to yield ketone derivative and SO through an intermed
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::397612f56e08609aea1709e94033d3e7
https://doi.org/10.1016/j.jmgm.2019.08.014
https://doi.org/10.1016/j.jmgm.2019.08.014