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Autor:
Justin N. D. Warne, and Robert Greatrex, Mingliang Jiang, Terence P. Kee, Caroline Ward, Julian P. Duxbury, Mark Thornton-Pett, Rashfeena Mushtaq
Publikováno v:
Organometallics. 19:4445-4457
Chiral complexes of aluminum containing the salcyen ligand framework, [(R,R)-salcyen]AlX (X = Me, OSiMe2tBu), catalyze the asymmetric addition of diorgano-H-phosphonates to carbonyls: the phospho-aldol reaction. Reaction proceeds smoothly at ambient