Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Rapolu Kiran Kumar"'
Publikováno v:
Tetrahedron Letters. 57:5730-5741
The combined chemistry of silver and isocyanides is unique in performance, proved with the number of recent achievements. With the aim of triggering further research in this field, this review assembles and comprehensively summarizes the silver-based
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7aa49d5d8a973f151fb4034b8547835c
https://doi.org/10.1016/j.tetlet.2016.11.005
https://doi.org/10.1016/j.tetlet.2016.11.005
Publikováno v:
Organic Letters. 18:4998-5001
Alcohols are among the most abundant and commonly used organic feedstock in industrial processes and academic research. The first tandem O-H insertion/[1,3]-alkyl shift reaction reported is between benzylic alcohols and rhodium azavinyl carbenoids de
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::85f0dda9f5c31b2b8f8ff1d6b3c723d4
https://doi.org/10.1021/acs.orglett.6b02459
https://doi.org/10.1021/acs.orglett.6b02459
Publikováno v:
Chemistry - An Asian Journal. 11:2841-2845
Imidazole ring is an important five-membered aromatic heterocycle that is widely present in natural products and synthetic molecules. The isocyanide-isocyanide [3+2] cross-cycloaddition reaction constitutes a straightforward method to access imidazol
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d0d2e18a96bf9719f92b506b07588b5f
https://doi.org/10.1002/asia.201601024
https://doi.org/10.1002/asia.201601024
Publikováno v:
Chemical Communications. 52:5936-5939
We report chemo- and regioselective direct reductive deoxygenation of 1-en-4-yn-3-ols into 1,4-enynes through FeF3 and TfOH cooperative catalysis under NBSH-mediated conditions. Further, we show the efficient synthesis of a pharmaceutically significa
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::322ab095da659d6ab709405c298403f7
https://doi.org/10.1039/c5cc10518h
https://doi.org/10.1039/c5cc10518h
Autor:
Xihe Bi, Rapolu Kiran Kumar
Publikováno v:
Chemical Communications. 52:853-868
The majority reactions of alkynes in the literature are reported to proceed via either structural σ-activation or catalytic π-activation of C≡C bonds. We skillfully designed novel methods for the catalytic σ-activation of C≡C bonds of alkynyl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8b48c1ec9626152572c7951125c895d1
https://doi.org/10.1039/c5cc08386a
https://doi.org/10.1039/c5cc08386a
Publikováno v:
Organic Letters. 17:6190-6193
The room-temperature nucleophilic addition of vinyl azides to propargylic alcohols under BF3·Et2O catalysis provides an efficient synthesis of 4-ynamides. The procedure is operationally convenient, shows broad substrate scope, and is viable for the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9d8c33eb87fc62cc1dcbd53a603c0f47
https://doi.org/10.1021/acs.orglett.5b03189
https://doi.org/10.1021/acs.orglett.5b03189
Publikováno v:
Synthesis. 47:2317-2346
Propargylic alcohols, which possess inherent alkynyl and hydroxyl functional groups, are one of the most valuable bifunctional building blocks in the field of organic synthesis. The simple generation and conversion of these compounds into various val
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d05847aa19e557caa1403e50103e43fa
https://doi.org/10.1055/s-0034-1378852
https://doi.org/10.1055/s-0034-1378852
Publikováno v:
ChemInform. 47
We report chemo- and regioselective direct reductive deoxygenation of 1-en-4-yn-3-ols into 1,4-enynes through FeF3 and TfOH cooperative catalysis under NBSH-mediated conditions. Further, we show the efficient synthesis of a pharmaceutically significa
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::74600d39f33d1ba99f77c1fdc2f1bf21
https://doi.org/10.1002/chin.201635037
https://doi.org/10.1002/chin.201635037
Publikováno v:
ChemInform. 47
The nucleophilic addition of vinyl azide (II) to propargylic alcohols (I) is accompanied by a Schmidt rearrangement to afford 4-ynamides, which are converted into dihydrofuranones by an intramolecular Vilsmeier cyclization.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9a779a4ff902f35890885a33d586538c
https://doi.org/10.1002/chin.201619088
https://doi.org/10.1002/chin.201619088
Autor:
Xihe Bi, Rapolu Kiran Kumar
Publikováno v:
ChemInform. 47
The majority reactions of alkynes in the literature are reported to proceed via either structural σ-activation or catalytic π-activation of CC bonds. We skillfully designed novel methods for the catalytic σ-activation of CC bonds of alkynyl compou
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::323e6dd34b92d0cc8f308012064a7f95
https://doi.org/10.1002/chin.201610236
https://doi.org/10.1002/chin.201610236