Zobrazeno 1 - 10
of 99
pro vyhledávání: '"Raphy Poupko"'
Autor:
Noga Friedman, Xiaolin Cao, Zeev Luz, Hailin Zheng, Herbert Zimmermann, Ellen J. Wachtel, Raphy Poupko, Teresa B. Freedman, Laurence A. Nafie
Publikováno v:
The Journal of Physical Chemistry A
The paper concerns the structural and optical isomers of nonamethoxy-tribenzocyclononene (compound 1). In the first part of the paper it is shown that 1 exists in two structural isomers: a rigid crown (c-1) with C3 symmetry and a flexible saddle (s-1
Publikováno v:
The Journal of Physical Chemistry B
Cyclotriveratrylene (CTV), or hexamethoxy tribenzocyclononatriene (hexamethoxy-TBCN) and other peripherally hexa-(or tri-)substituted TBCN were so far only known to exist in their crown form. Attempts to detect the corresponding saddle isomers failed
Publikováno v:
Molecular Crystals and Liquid Crystals
A new homologous series of compounds, nonaalkanoyloxy tribenzocyclononene (TBCN-n, where n is the number of carbons per side chain) with n = 2 to 14 was synthesized. The compounds exist in two isomeric forms, crown and saddle. For sufficiently long s
Publikováno v:
Journal of the American Chemical Society
Nona-alkanoyloxy tribenzocyclononene (CTV-n, where n is the number of carbons in the side chains) were prepared for n = 2 to 14. The homologues of this series appear in two stable isomeric forms, rigid crown and flexible saddle. We report on their is
Publikováno v:
The Journal of Chemical Physics. 115:8049-8059
The title compound, 1,2-dichloro-3,4,5,6-tetramethylbenzene (DCTMB) exhibits three solid phases, III, II, and I, of which two, Phase III (
Autor:
Heike Schmitt, Detlef Reichert, Herbert Zimmermann, Thomas Bräuniger, Raphy Poupko, Ulrich Haeberlen, Zeev Luz
Publikováno v:
Physical Chemistry Chemical Physics
Deuterium NMR measurements on powder and single crystal samples of 1,2,3-trichloro-4,5,6-trimethylbenzene (TCTMB) specifically deuterated at the central methyl group (TCTMB-d3) are reported. The compound exhibits three solid phases: (I) A high temper
Publikováno v:
Journal of the American Chemical Society
Phosphorus-31 NMR measurements are reported on solid Li3P7(monoglyme)3 in the temperature range −90 to +70 °C, under both, nonspinning and magic angle spinning (MAS) conditions. At low temperatures (
Publikováno v:
Solid State Nuclear Magnetic Resonance. 13:137-148
One- (1-D) and two-dimensional (2-D) carbon-13 NMR exchange measurements in powder samples of isotopically normal durene under magic angle spinning (MAS) are reported. The experiments include rotor synchronized 2-D exchange (RS2DE), 1-D magnetization
Publikováno v:
Liquid Crystals
The preparation and mesomorphic properties of four members of the homologous series of dimers, alkandioic acid bis\[pentakis(n -heptanoyloxy)phenyl] esters \[(C6 H13 COO)5 C6 OC(O)(CH2)(n-2)/2]2 with n= 6, 8, 12 and 14, are reported. They are hencefo
Publikováno v:
The Journal of Physical Chemistry A. 101:5097-5102
Carbon-13 NMR is used to study the tautomeric equilibrium of citrinin in the solid state. The results confirm earlier X-ray diffraction studies, which indicated that the compound crystallizes in a disordered structure, with the p-quinone and o-quinon