Zobrazeno 1 - 10
of 83
pro vyhledávání: '"Raoul Uzan"'
Publikováno v:
Tetrahedron Letters. 38:7733-7736
Regioselective bromination of D-pentono-1,4-lactones with SOBr 2 in DMF led to 5-bromo-5-deoxy derivatives. These intermediates were treated with LiN 3 and hydrogenated to give 5-amino-5-deoxy-D-pentonolactams in 60–83% overall yield.
Publikováno v:
Journal of Carbohydrate Chemistry. 16:1089-1100
C-6 ring opening of 5,6-cyclic sulfate derivatives of protected manno and glucofuranose with carbohydrate alkoxides gave ether linked pseudo-di or trisaccharides. Use of methyl 2,3-O-isopropylidene...
Publikováno v:
Synthesis. 1997:925-930
Publikováno v:
Carbohydrate Research. 300:139-142
Treatment of unprotected d -ribono, d -arabinono and d -xylono-1,4-lactones with either thionyl chloride or thionyl bromide in dimethylformamide led to 5-chloro- or 5-bromo-5-deoxy derivatives in 70%–95% yields. Under the same conditions, d -lyxono
Publikováno v:
Tetrahedron Letters. 37:49-52
Reaction of cysteamine with d-ribofuranose in which a 2,3-O-isopropylidene group was introduced, yielded the 2-(S)-thiazolidine derivative stereoselectively. The following step of cyclisation led to castanospermine and australine analogues, 3 and 4,
Publikováno v:
Carbohydrate Research. 275:421-431
Publikováno v:
Tetrahedron Letters. 36:383-386
Treatment of partially protected or unprotected carbohydrates with the RhH(PPh 3 ) 4 -benzalacetone system leads exclusively to glycono-1,4-lactones by regioselective oxidation and subsequent ring restriction.
Publikováno v:
Journal of Carbohydrate Chemistry. 13:967-979
Treatment of unprotected hexitols (D-glucitol, D-mannitol) and pentitols (D-arabinitol, xylitol and ribitol) with 1-chlorocarbonyl-1-methylethyl acetate (Me2C(OAc)COCl), in 1,4-dioxane, leads to α,ω-dichloro derivatives in good yields. A route to s
Publikováno v:
Carbohydrate Research. 262:147-154
Publikováno v:
Tetrahedron Letters. 35:6279-6282
In a one-pot procedure, treatment of partially protected D-glucose and unprotected D-xylose, with N,N″-thionyldiimidazole and then phenoxide ions gives stereoselectively β-O-aryl glycosides.