Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Ramona Metzinger"'
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 10, Pp o2687-o2687 (2010)
The title compound, C17H24O2, is the product of a haloform reaction of 6-acetyl-1,1,2,4,4,7-hexamethyltetraline (AHTN). The compound is a racemic mixture with a disorder in its aliphatic ring [occupany ratio 0.683 (4):0.317 (4)] due to two possible h
Externí odkaz:
https://doaj.org/article/66e0fb518abf4f93ababe06ebbafe3e9
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 642:1198-1206
While addition of [Cp2ReH] to [Bi(OtBu)3] leads to an equilibrium containing [Cp2Re-Bi(OtBu)2], [{Cp2Re}2Bi(OtBu)], tBuOH and [CpRe(μ-η5,η1-C5H4)Bi–ReCp2], in the presence of water [{(Cp2Re)2Bi}2O] (1) is formed selectively. Also [FpH] [Fp = (η
Autor:
Ramona Metzinger, Sjoerd Harder, Beatrice Braun, Christian Herwig, Christian Limberg, Henrike Gehring, Kallol Ray
Publikováno v:
Dalton Transactions. 45:2989-2996
After lithiation of PYR-H2 (PYR = [(NC(Me)C(H)C(Me)NC6H3(iPr)2)2(C5H3N)](2-)) - the precursor of an expanded β-diketiminato ligand system with two binding pockets - with KN(TMS)2 the reaction of the resulting potassium salt with FeBr2 led to a dinuc
Publikováno v:
Chemistry - A European Journal. 21:1198-1207
New tripodal ligand L2 featuring three different pyridyl/imidazolyl-based N-donor units at a bridgehead C atom, from which one of the imidazolyl units is separated by a phenylene linker, was synthesized and investigated with regards to copper(I) comp
Publikováno v:
Chemistry - A European Journal. 20:4721-4735
A novel redox-active ligand, H4(Ph2S)L(AP) (1) which was designed to be potentially pentadentate with an O,N,S,N,O donor set is described. Treatment of 1 with two equivalents of potassium hydride gave access to octametallic precursor complex [H2(Ph2S
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 639:2426-2432
Previous attempts to synthesize and isolate (thiobisphenolate) vanadium(V) dioxido complexes had always provided their dimers containing [O=V(μ-O)2V=O]2+ cores, and these also dominate the solution reactivity. Hence, the behavior of their parent mon
Publikováno v:
Zeitschrift für Naturforschung B. 68:561-568
Reaction of equimolar amounts of [Bi(OtBu)3] and [Cp2ReH] yields [Cp2Re-Bi(OtBu)2], 1, when the reaction time is kept short. Treatment of [Bi{OCH(CF3)2}3(thf)]2 with four equivalents of [Cp2ReH] leads to the heterotrinuclear complex [(Cp2Re)2Bi{OCH(C
Publikováno v:
European Journal of Inorganic Chemistry. 2013:3937-3942
A (β-diketiminato)nickel(II) hydrazido(1–) complex [LtBuNi(η2-N2H3)], {1, LtBu = [HC(CtBuNC6H3{iPr}2)2]–} has been obtained by treatment of [LtBuNiBr] with hydrazine. In a reaction of 1 with two equivalents of the azo compound diisopropyl azodi
Autor:
Henrike Gehring, Christian Herwig, Christian Limberg, Sjoerd Harder, Ramona Metzinger, Julia Intemann
Publikováno v:
Chemistry, 19(5), 1629-1636. Wiley-VCH Verlag GmbH & Co. KGaA
After the lithiation of PYR-H(2) (PYR(2-) =[{NC(Me)C(H)C(Me)NC(6)H(3)(iPr)(2)}(2)(C(5)H(3)N)](2-)), which is the precursor of an expanded β-diketiminato ligand system with two binding pockets, its reaction with [NiBr(2) (dme)] led to a dinuclear nic
Publikováno v:
Chemistry - A European Journal. 18:15449-15458
The two different coordination spheres afforded by Pacman architectures offer cooperativity derived from two different metal centers. A modular strategy is developed to produce a hetero-Pacman scaffold featuring a porphyrin and terpyridine for metal-