Zobrazeno 1 - 10
of 45
pro vyhledávání: '"Ramjee Balasubramanian"'
Publikováno v:
Sensors and Actuators B: Chemical. 247:706-712
In this article, we show that resorcinarene tetratrimethylammonium tetrabromide cavitand interdigitated gold nanoparticles can be prepared by appropriate choice of solvent and that they can act as efficient colorimetric sensors for the selective dete
Autor:
Ramjee Balasubramanian
Wet-chemical methods have enabled the size-, shape- and composition-controlled synthesis of bi- and multi-metallic nanoparticles with varying degrees of success. Among several variables involved in colloidal synthesis, coordination ligands surroundin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::df203c9ad28abe10be68895197c247ed
https://doi.org/10.1039/9781782620358-00001
https://doi.org/10.1039/9781782620358-00001
Autor:
Ramjee Balasubramanian, Sangbum Han
Publikováno v:
Langmuir. 30:9063-9070
Resorcinarenes with three different quaternary ammonium headgroups were synthesized and evaluated for their ability to stabilize gold nanoparticles in organic and aqueous medium. Aqueous dispersions of citrate stabilized gold nanoparticles of dimensi
Autor:
Rebecca L. Stiles, Jai Pil Choi, Alicia D. Douglas, Christina A. Fields-Zinna, Royce W. Murray, Matthew C. Crowe, Ramjee Balasubramanian
Publikováno v:
The Journal of Physical Chemistry C. 114:15890-15896
We report reactivity of the gold nanoparticle [TOA+] [Au25(SC2Ph)18]1− (TOA+ = tetraoctylammonium; SC2Ph = phenylethanethiolate = L; [Au25(SC2Ph)18]1− = Au25L181−) with Ag+, Cu2+, and Pb2+ ions. Titration of solutions of Au25L181− in CH2Cl2 w
Electron Transport and Counterion Relaxation Dynamics in Neat Ferrocenated Imidazolium Ionic Liquids
Publikováno v:
The Journal of Physical Chemistry C. 112:18207-18216
The electron transport properties of 12 imidazolium ionic liquids (ILs) in which ferrocene groups have been attached to the imidazolium center by different linkers have been investigated. Cobalticenium is alternatively attached in another ionic liqui
Publikováno v:
Journal of the American Chemical Society. 130:1856-1865
Au nanoparticles fully coated with omega-ferrocenyl hexanethiolate ligands, with average composition Au225(omega-ferrocenyl hexanethiolate)43, exhibit a unique combination of adsorption properties on Pt electrodes. The adsorbed layer is so robust tha
Autor:
Amala Dass, Ramjee Balasubramanian, Royce W. Murray, Rui Guo, Joseph B. Tracy, and Alicia D. Douglas
Publikováno v:
Langmuir. 24:310-315
Two syntheses of gold nanoparticles with fluorinated alkyl and aryl thiolate ligands are reported. The fluorous Au nanoparticles are smaller than previous gold fluor-capped examples, and are in the 44-75 Au atom size range. Fluoroalkyl thiolate-prote
Publikováno v:
J. Mater. Chem.. 17:105-112
Two resorcinarene-derived tetrathiols with terminal alkene sidechains (tetraarylthiol cavitand 3 and tetrabenzylthiol cavitand 4) were determined to be efficient at extracting colloidal gold nanoparticles from aqueous solutions and stabilizing their
Publikováno v:
Langmuir. 23:2247-2254
The synthesis and compositional analysis of four different gold clusters with protecting monolayers comprised solely of ferrocene hexanethiolate ligands is described. The gold nanoparticles have average core diameters of 1.4, 1.6, 2.0, and 2.2 nm wit
Publikováno v:
Journal of the American Chemical Society. 127:8126-8132
This paper describes the reaction of the phosphine-protected Au nanoparticle Au(55)(PPh(3))(12)Cl(6) (1, "Au55") with hexanethiol (2) and other thiols. The voltammetry of the reaction product 2 displays a well-defined pattern of peaks qualitatively r