Zobrazeno 1 - 10
of 89
pro vyhledávání: '"Ram P. Kashyap"'
Publikováno v:
Inorganic Chemistry. 41:7113-7124
A series of new (silylamino)phosphines that contain sterically bulky silyl groups on nitrogen were prepared by deprotonation/substitution reactions of the hindered disilylamines t-BuR(2)Si(Me(3)Si)NH (1, R = Me; 2, R = Ph) and (Et(3)Si)(2)NH (3). Seq
Autor:
Ram P. Kashyap, Mariusz Krawiec, Lawrence D. Fitz, Lance M. Williams, Susan A. Bourne, William H. Watson, Richard B. Walker
Publikováno v:
Journal of Chemical Crystallography. 27:35-44
The rates of hydrolysis of oxazolidines with ortho-hydroxyphenyl substituents at C(2) are more than 30 times faster than oxazolidines with para-hydroxyphenyl substituents. The later rates are identical to those with a phenyl group at C(2) indicating
Autor:
Ram P. Kashyap, William H. Watson, Zuyue Du, Florencio Zaragoza, Zenghui Liu, D. Vidyanand, Herman L. Ammon, L. Kathleen Talafuse, Alan P. Marchand, Kaipenchery A. Kumar, Simon G. Bott
Publikováno v:
Tetrahedron. 52:9703-9712
Polycyclic bis-epoxides 5, 6, and 7 have been synthesized, and their structures established unequivocally via application of single crystal X-ray crystallographic methods. The crystal densities of 2–7 (calculated from X-ray crystallographic data) a
Publikováno v:
Synthetic Communications. 26:819-825
HEXACYCLO[7.4.0.02,8.03,7.06,11]tridecane-10,13-dione (“homosecohexaprismane-10,13-dione”, 8) has been prepared via a six-step sequence that results in homologation of two of the cyclopentane rings in pentacyclo[5.4.0.02,6.03,10.05,9]-undecane-8,
Autor:
Mahendra N. Deshpande, Dayanada Rajapaksa, Alan P. Marchand, Ram P. Kashyap, William H. Watson
Publikováno v:
Journal of Chemical Crystallography. 25:573-578
Hexacyclo[6.5.0.02,7.04,12.05,10.09.13]tridecane (HCTD) contains two four-membered, two five-membered and two six-membered rings fused into a cage structure which contains about 77.0 kcal/mol of strain energy. Attempts to prepare the thioketal from t
Autor:
Robert A. Gau, Douglas N. Butler, Paul M. Tepperman, Ronald N. Warrener, Ram P. Kashyap, William H. Watson
Publikováno v:
Tetrahedron Letters. 36:6145-6148
New rigid cavity molecules are described in which bromides, epoxides, olefins, alcohols and acetates are positioned such that there is direct line of sight between them. Examples are provided of systems where the separation distances are in the range
Publikováno v:
Journal of Chemical Crystallography. 25:339-349
The stepwise addition of thiophenol to benzoquinone gives thiophenylbenzoquinone (1b), 2,5-and 2,6-di-(thiophenyl)benzoquinone (2,3),2,3,6-tri(thiophenyl)benzoquinone (4) and 2,3,5,6-tetra(thiophenyl)benzoquinone. (5). Compounds1–4 can be crystalli
Publikováno v:
Journal of the American Chemical Society. 117:586-601
Publikováno v:
Journal of Chemical Crystallography. 24:627-638
Seven β2 complexes have been investigated and the structural parameters compared with literature values and molecular mechanics calculations. All β2 compounds exhibit the (S,S,λλδ) or, (R,R,δδλ) configuration. Three of the β2 complexes have
Autor:
Ram P. Kashyap, William H. Watson, Mariusz Krawiec, Yanjun Wang, Thomas F. Carlson, Duoli Sun, Alan P. Marchand
Publikováno v:
Journal of Chemical Crystallography. 24:259-266
2,8,10,11-Tetrachloro-12-oxahexacyclo[7,2.1.02.8.03.7.04.11.06.10]dodeca-1,9-diol is a strained cage molecule containing six five-membered rings and a four-membered ring. Twenty-five of the internal angles are less than 105° with 6 ranging from 89.5