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pro vyhledávání: '"Ramón M. Sánchez"'
An unexpected bicyclic pyrrolidinedione by rearrangement of the β-lactam ring under basic conditions
Publikováno v:
ARKIVOC, Vol 2010, Iss 3, Pp 228-236 (2009)
Externí odkaz:
https://doaj.org/article/4ec357b434aa4e97bbf50e2a11861d7f
Publikováno v:
Tetrahedron. 74:5415-5426
A Staudinger reaction between methoxyketene and two different imines formed from citral afforded, after chemical transformation, the (E/Z)-4-alkenylepoxy-2-azetidinones 2, 3 and 4. These compounds, by reaction with Cp2TiCl, did not cyclize to afford
Autor:
Josefa Anaya, Ramón M. Sánchez
Publikováno v:
Progress in Heterocyclic Chemistry ISBN: 9780323898126
Progress in Heterocyclic Chemistry ISBN: 9780323984102
Progress in Heterocyclic Chemistry ISBN: 9780443189395
Progress in Heterocyclic Chemistry ISBN: 9780323984102
Progress in Heterocyclic Chemistry ISBN: 9780443189395
The review covers work published in the calendar year 2015. The synthesis and reactivity of four-membered heteroatom-containing cycles are reviewed. New developments in the chemistry of these strained heterocycles, especially β-lactams, are covered.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a1de5ad0f07426342a987f8ec036b980
https://doi.org/10.1016/b978-0-08-102788-2.00004-0
https://doi.org/10.1016/b978-0-08-102788-2.00004-0
An unexpected bicyclic pyrrolidinedione by rearrangement of the β-lactam ring under basic conditions
Publikováno v:
ARKIVOC, Vol 2010, Iss 3, Pp 228-236 (2009)
During synthetic studies on anti-elastase polycyclic β-lactams from conveniently substituted monolactams, we attempted to obtain an N-(1 -methoxycarbonyalkylidene)-β-lactam by αselenoxide elimination. Although the desired alkenes 5 were obtained,