Zobrazeno 1 - 10
of 71
pro vyhledávání: '"Ralph A. Whitney"'
Publikováno v:
Rubber Chemistry and Technology. 92:350-363
The importance of dehydrobromination to the cure chemistry of brominated butyl rubber (BIIR) is demonstrated through a combination of cure rheometry studies and model compound experiments. These data show that, while HBr elimination to give an exomet
Publikováno v:
The Canadian Journal of Chemical Engineering. 96:83-90
The development of new peroxide-curable poly(isobutylene-co-isoprene) (IIR) elastomers is described, wherein pendant oligomerizable C=C groups are introduced in combination with a range of serviceable functional groups. Ring-opening of itaconic anhyd
Publikováno v:
Reactive and Functional Polymers. 106:69-75
Elastomeric ionomers are prepared via halide displacement from brominated poly(isobutylene-co-isoprene) (BIIR) with various imidazole-based nucleophiles. Reaction of BIIR with imidazole or 1,1′(1,4-butanediyl)bis(imidazole) in a single-step, solven
Autor:
Ralph A. Whitney, Omar Garcia-Valdez, Ryan D. Roeder, Pascale Champagne, Michael F. Cunningham
Publikováno v:
Polymer Chemistry. 7:6383-6390
Cellulose nanocrystals (CNC) have become the subject of increasing research interest because of their unique physical, chemical and mechanical properties, including being a renewable material. While CNC shows promise as a reinforcing material in poly
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 53:2800-2808
Crystalline nanocellulose (CNC) was grafted with poly(methyl acrylate) (PMA) to yield modified CNC that is readily dispersed in a range of organic solvents [including tetrahydrofuran, chloroform, dimethylformamide, and dimethyl sulfoxide (DMSO)], in
Autor:
Pascale Champagne, Ralph A. Whitney, Ronald J. Neufeld, Vitaliy Kapishon, Michael F. Cunningham
Publikováno v:
Biomacromolecules. 16:2040-2048
Alginate-based amphiphilic graft copolymers were synthesized by single electron transfer living radical polymerization (SET-LRP), forming stable micelles during polymerization induced self-assembly (PISA). First, alginate macroinitiator was prepared
Publikováno v:
Industrial & Engineering Chemistry Research. 53:17527-17536
A series of new elastomeric ionomers is prepared through halide displacement from brominated poly(isobutylene-co-para-methylstyrene) (BIMS) by a range of N-substituted imidazoles. Studies of the dynamics of solvent-borne and solvent-free reactions de
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 51:2438-2444
Publikováno v:
Macromolecular Reaction Engineering. 7:237-253
A mathematical model is developed for condensation polymerization of 1,3-propanediol to produce Cerenol polyether. The effect of the super-acid catalyst is considered explicitly in the proposed reaction mechanism. The main reactions include protonati
Autor:
Michael F. Cunningham, Ralph A. Whitney, Vitaliy Kapishon, Ronald J. Neufeld, Stephanie Allison, Myron R. Szewczuk
Publikováno v:
Biomaterials science. 4(3)
Targeted drug delivery using polymeric nanostructures has been at the forefront of cancer research, engineered for safer, more efficient and effective use of chemotherapy. Here, we designed a new polymeric micelle delivery system for active tumor tar