Zobrazeno 1 - 10
of 162
pro vyhledávání: '"Ralf Miethchen"'
Publikováno v:
European Journal of Inorganic Chemistry. 2018:1302-1308
Autor:
Carl‐Friedrich Kröger, Ralf Miethchen
Publikováno v:
Zeitschrift für Chemie. 15:135-141
Autor:
Ralf Miethchen
Publikováno v:
Zeitschrift für Chemie. 29:425-434
The present review discusses reactions of unprotected and protected carbohydrates in hydrogen fluoride as well as the synthesis of fluorinated carbohydrates by use of anhydrous liquid hydrogen fluoride or Systems containing hydrogen fluoride (e.g. HF
Publikováno v:
Carbohydrate Research. 341:2641-2652
The dithionite-mediated addition of BrCF(2)Cl to 3,4-di-O-pivaloyl-D-xylal (1) generated preferably 1-CF(2)Cl-substituted products, that is, (2-bromo-2-deoxy-3,4-di-O-pivaloyl-beta-D-xylopyranosyl)-chlorodifluoromethane and (2-deoxy-3,4-di-O-pivaloyl
Publikováno v:
Synthesis. 2006:2685-2692
Regioselective one-pot O-silylation reactions of 1,2-O-isopropylidene-α-D-glucofuranose and 1,2-0-isopropylidene-β-D-fructopyranose using bulky oligosilyl groups are described. Some new silylating reagents (oligosilyl bistriflates), which were gene
Publikováno v:
Carbohydrate Research. 341:1758-1763
A convenient two-step strategy is reported for the synthesis of fluorinated optically pure acyclo-C-nucleoside analogues starting from simple glycals. In the first step, benzyl- or p-methoxybenzyl-protected glycals are treated with trifluoroacetic an
Autor:
Anita Wegert, Richard Plantier-Royon, Norbert Hoffmann, Charles Portella, Jean-Bernard Behr, Ralf Miethchen
Publikováno v:
Synthesis. 2006:2343-2348
An efficient procedure was established to synthesize a thymidine analogue bearing an acylsilane function at the 5¢-posi- tion, starting from thymidine in four steps and 58% overall yield. This compound proved to be a valuable intermediate for the sy
Publikováno v:
Tetrahedron. 62:3301-3308
The halogenated 1 H -1,2,4-triazole glycosides 6 – 10 were synthesized by BF 3 -activated glycosylation of 3(5)-chloro-1,2,4-triazole ( 2 ), 3,5-dichloro-1,2,4-triazole ( 3 ), 3,5-dibromo-1,2,4-triazole ( 4 ), and 3(5)-bromo-5(3)-chloro-1,2,4-triaz
Autor:
Helmut Reinke, Martin Köckerling, Ralf Miethchen, Stefanie Libnow, Andrea Christiansen, Susanne Wille, Martin Hein
Publikováno v:
Synthesis. :496-508
1.2.4-Triazole nucleoside analogues bonded at N-1 of the base were synthesized by addition of N-halo-3,5-dibromo-1,2,4-triazoles to 1,2-unsaturated carbohydrate derivatives (glycals). Examples are given for l,5-anhydro-3,4,6-tri-O-acetyl-2-deoxy-D-ar
Publikováno v:
Synthesis. 2005:1850-1858
The dithionite-mediated chlorodifluoromethylations of 3,4-di-O-acetyl-1,5-anhydro-2,6-dideoxy-L-arabino-hex-1-enitol (1), 1,5-anhydro-2,3,4-tri-O-pivaloyl-D-erythro-pent-1-enitol (13), 2,3,4-tri-O-acetyl-1,5-anhydro-6-deoxy-L-lyxo-hex-1-enitol (15),