Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Rajith S. Manan"'
Autor:
Rajith S. Manan, Pinjing Zhao
Publikováno v:
Nature Communications, Vol 7, Iss 1, Pp 1-11 (2016)
C–H activations and hydroaminations are useful synthetic procedures for building up complex, functional molecules. Here, the authors report a single catalyst capable of performing tandem C–H activation and hydroamination, giving access to N-heter
Externí odkaz:
https://doaj.org/article/1eadc2309b74490a95a6d8f34cbf5eb0
Publikováno v:
Nature Biomedical Engineering.
Autor:
Jian Wang, Rajith S. Manan, Pinjing Zhao, Angel Ugrinov, Taehyun Kim, Zhongyu Yang, Junfeng Liu, Yanxiong Pan
We report a method for mild and atom-efficient synthesis of ketazines via nickel-catalyzed intermolecular hydroamination of internal alkynes with NH2-hydrazones. This alkyne hydrohydrazonation process is promoted by [Ni(cod)2] as a Ni(0) precatalyst
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2859775b3542002a80e4bab7b30d4c2e
https://doi.org/10.33774/chemrxiv-2021-p8b6f
https://doi.org/10.33774/chemrxiv-2021-p8b6f
Publikováno v:
ACS Catalysis. 9:5881-5889
Catalytic site-selective hydroallylation of vinyl arenes and 1,3-dienes is reported. Transformations are promoted by a readily accessible bidentate carbodicarbene–rhodium complex and involve commer...
Publikováno v:
Advanced Drug Delivery Reviews. 178:113834
Recent medical advances have exploited the ability to address a given disease at the underlying level of transcription and translation. These treatment paradigms utilize nucleic acids - including short interfering RNA (siRNA), microRNA (miRNA), antis
Publikováno v:
Journal of the American Chemical Society. 139(44)
Catalytic enantioselective addition of N-heteroarenes to terminal and internal 1,3-dienes is reported. Reactions are promoted by 5 mol % of Rh catalyst supported by a new chiral pincer carbodicarbene ligand that delivers allylic substituted arenes in
Publikováno v:
Organic letters. 19(1)
Catalytic intermolecular hydroalkylation of dienes with silyloxyfuran nucleophiles is reported. Reactions are catalyzed by 5 mol % of a (CDC)-Rh complex and proceed in up to 87% yield and 6:1 dr (syn/anti) to provide allylic butenolides bearing vicin
Publikováno v:
ChemInform. 46
An efficient and scalable procedure for the transformation of diaryl or alkylarylimines with dialkyl, diaryl, or alkylarylalkynes is developed which provides 2-aza-1,3-dienes exclusively as (Z)-isomers.
Autor:
Pinjing Zhao, Rajith S. Manan
Publikováno v:
Nature Communications
Nature Communications, Vol 7, Iss 1, Pp 1-11 (2016)
Nature Communications, Vol 7, Iss 1, Pp 1-11 (2016)
Catalytic C–H activation and hydroamination represent two important strategies for eco-friendly chemical synthesis with high atom efficiency and reduced waste production. Combining both C–H activation and hydroamination in a cascade process, pref
Publikováno v:
Journal of the American Chemical Society. 137(19)
A modular and atom-efficient synthesis of 2-aza-1,3-butadiene derivatives has been developed via nickel-catalyzed intermolecular coupling between internal alkynes and aromatic N-H ketimines. This novel alkyne hydroimination process is promoted by a c