Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Rajiha A. Saadalla-Nazhat"'
Autor:
Kevin Fairburn, Peter Jones, David R. Blake, Bo R. Nielsen, Rajiha A. Saadalla-Nazhat, Paul G. Winyard, Najdat B. Nazhat, Martyn C. R. Symons
Publikováno v:
ResearcherID
DBNBS (3,5-dibromo-4-nitrosobenzenesulphonate) reacts with nitric oxide (NO) produced from nitrite ions in acid solution to give a radical with a characteristic electron spin resonance spectrum, attributable to a ‘DBNBS-NO’ product, and comprisin
Autor:
Helen E. Wilkin, Thomas E. G. Candy, David R. Blake, Najdat B. Nazhat, Peter Jones, Guang Yang, Marta Boaro, Rajiha A. Saadalla-Nazhat
Publikováno v:
Free Radical Biology and Medicine. 12:327-330
A recent study reports discordant results for maximal free-radical yields from the decomposition of peroxynitrous acid using different assay reagents and a puzzling decrease (to zero) of the radical yields with increasing pH. An assay method using 2,
Publikováno v:
Analytica Chimica Acta. 204:349-353
The procedure described for the determination of hydrogen peroxide in aqueous solution, at concentrations in the rnage 1−120×10−6 mol l−1, is based on reduction of copper (II) ions by hydrogen peroxide in the presence of excess of 2,9-dimethyl
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :407
Kinetic evidence support the formation of a copper(III) species, rather than the hydroxyl free radical, when the aquocopper(I) ion reacts hydrogen peroxide in aqueous solution.
Publikováno v:
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 80:2759
Ligand decomposition following charge-transfer excitation of bis(glycinato)cuprate(II) in aqueous solution gives NH3 and HCHO as the final products in yields equivalent to the reduction of the metal to CuI. An intermediate, observed by flash photolys
Publikováno v:
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 85:677
Reactions of the hydroxyl radical (OH˙) in amino acid (glycine and α-alanine)–copper(II) aqueous systems have been investigated by measurement of the γ-radiation yields of the products: ammonia, formaldehyde and glyoxylic acid (from glycine), ac
Publikováno v:
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 84:501
Oxidation of CH3OH to HCHO occurs as a chain reaction on γ-irradiation of deaerated aqueous CH3OH + H2O2+ Cu2+aq solutions. The reaction of Cu+aq with H2O2 is a propagation step. The chain-length and the dependence of HCHO formation rate on radiatio